Cargando…
Methyl (2Z)-2-[(2-formyl-3-methyl-1H-indol-1-yl)methyl]-3-(4-methoxyphenyl)prop-2-enoate
In the title indole derivative, C(22)H(21)NO(4), the dihedral angle between the benzene and pyrrole rings of indole moiety is 1.8 (1)°. The plane of the 4-methoxyphenyl ring is oriented with a dihedral angle of 60.7 (1)° with respect to the plane of the indole moiety. The molecular packing is sta...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998543/ https://www.ncbi.nlm.nih.gov/pubmed/24826139 http://dx.doi.org/10.1107/S1600536814005261 |
| _version_ | 1782313383882653696 |
|---|---|
| author | Selvanayagam, S. Sridhar, B. Kathiravan, S. Raghunathan, R. |
| author_facet | Selvanayagam, S. Sridhar, B. Kathiravan, S. Raghunathan, R. |
| author_sort | Selvanayagam, S. |
| collection | PubMed |
| description | In the title indole derivative, C(22)H(21)NO(4), the dihedral angle between the benzene and pyrrole rings of indole moiety is 1.8 (1)°. The plane of the 4-methoxyphenyl ring is oriented with a dihedral angle of 60.7 (1)° with respect to the plane of the indole moiety. The molecular packing is stabilized by C—H⋯O hydrogen bonds which form a V-shaped chain arrangement along the bc plane of the unit cell. In addition to this, C—H⋯π and π–π interactions [centroid–centroid distances = 3.8102 (11) and 3.8803(12) Å], which run along the b-axis direction, stabilize the molecular packing. |
| format | Online Article Text |
| id | pubmed-3998543 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-39985432014-05-13 Methyl (2Z)-2-[(2-formyl-3-methyl-1H-indol-1-yl)methyl]-3-(4-methoxyphenyl)prop-2-enoate Selvanayagam, S. Sridhar, B. Kathiravan, S. Raghunathan, R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title indole derivative, C(22)H(21)NO(4), the dihedral angle between the benzene and pyrrole rings of indole moiety is 1.8 (1)°. The plane of the 4-methoxyphenyl ring is oriented with a dihedral angle of 60.7 (1)° with respect to the plane of the indole moiety. The molecular packing is stabilized by C—H⋯O hydrogen bonds which form a V-shaped chain arrangement along the bc plane of the unit cell. In addition to this, C—H⋯π and π–π interactions [centroid–centroid distances = 3.8102 (11) and 3.8803(12) Å], which run along the b-axis direction, stabilize the molecular packing. International Union of Crystallography 2014-03-15 /pmc/articles/PMC3998543/ /pubmed/24826139 http://dx.doi.org/10.1107/S1600536814005261 Text en © Selvanayagam et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Selvanayagam, S. Sridhar, B. Kathiravan, S. Raghunathan, R. Methyl (2Z)-2-[(2-formyl-3-methyl-1H-indol-1-yl)methyl]-3-(4-methoxyphenyl)prop-2-enoate |
| title | Methyl (2Z)-2-[(2-formyl-3-methyl-1H-indol-1-yl)methyl]-3-(4-methoxyphenyl)prop-2-enoate |
| title_full | Methyl (2Z)-2-[(2-formyl-3-methyl-1H-indol-1-yl)methyl]-3-(4-methoxyphenyl)prop-2-enoate |
| title_fullStr | Methyl (2Z)-2-[(2-formyl-3-methyl-1H-indol-1-yl)methyl]-3-(4-methoxyphenyl)prop-2-enoate |
| title_full_unstemmed | Methyl (2Z)-2-[(2-formyl-3-methyl-1H-indol-1-yl)methyl]-3-(4-methoxyphenyl)prop-2-enoate |
| title_short | Methyl (2Z)-2-[(2-formyl-3-methyl-1H-indol-1-yl)methyl]-3-(4-methoxyphenyl)prop-2-enoate |
| title_sort | methyl (2z)-2-[(2-formyl-3-methyl-1h-indol-1-yl)methyl]-3-(4-methoxyphenyl)prop-2-enoate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998543/ https://www.ncbi.nlm.nih.gov/pubmed/24826139 http://dx.doi.org/10.1107/S1600536814005261 |
| work_keys_str_mv | AT selvanayagams methyl2z22formyl3methyl1hindol1ylmethyl34methoxyphenylprop2enoate AT sridharb methyl2z22formyl3methyl1hindol1ylmethyl34methoxyphenylprop2enoate AT kathiravans methyl2z22formyl3methyl1hindol1ylmethyl34methoxyphenylprop2enoate AT raghunathanr methyl2z22formyl3methyl1hindol1ylmethyl34methoxyphenylprop2enoate |