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2-{2,4,6-Tris(bromomethyl)-3,5-bis[(1,3-dioxoisoindolin-2-yl)methyl]benzyl}isoindoline-1,3-dione toluene monosolvate
In the title compound, C(36)H(24)Br(3)N(3)O(6)·C(7)H(8), the toluene solvent molecule is associated with the receptor molecule via C—H⋯π bonding. The planes of the phthalimido groups are inclined at 77.0 (1), 63.0 (1) and 77.8 (1)° with respect to the benzene ring. The molecular conformation is s...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998546/ https://www.ncbi.nlm.nih.gov/pubmed/24826115 http://dx.doi.org/10.1107/S1600536814004383 |
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author | Koch, Niklas Seichter, Wilhelm Mazik, Monika |
author_facet | Koch, Niklas Seichter, Wilhelm Mazik, Monika |
author_sort | Koch, Niklas |
collection | PubMed |
description | In the title compound, C(36)H(24)Br(3)N(3)O(6)·C(7)H(8), the toluene solvent molecule is associated with the receptor molecule via C—H⋯π bonding. The planes of the phthalimido groups are inclined at 77.0 (1), 63.0 (1) and 77.8 (1)° with respect to the benzene ring. The molecular conformation is stabilized by C—H⋯O and C—H⋯Br hydrogen bonds. The crystal structure features non-classical hydrogen bonds of the C—H⋯N, C—H⋯O and C—H⋯Br type, leading to a three-dimensional cross-linking of molecules. The pattern of non-covalent intermolecular bonding is completed by O⋯Br halogen bonds [3.306 (3) Å], which link the receptor molecules into infinite strands extending along the a-axis direction. |
format | Online Article Text |
id | pubmed-3998546 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39985462014-05-13 2-{2,4,6-Tris(bromomethyl)-3,5-bis[(1,3-dioxoisoindolin-2-yl)methyl]benzyl}isoindoline-1,3-dione toluene monosolvate Koch, Niklas Seichter, Wilhelm Mazik, Monika Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(36)H(24)Br(3)N(3)O(6)·C(7)H(8), the toluene solvent molecule is associated with the receptor molecule via C—H⋯π bonding. The planes of the phthalimido groups are inclined at 77.0 (1), 63.0 (1) and 77.8 (1)° with respect to the benzene ring. The molecular conformation is stabilized by C—H⋯O and C—H⋯Br hydrogen bonds. The crystal structure features non-classical hydrogen bonds of the C—H⋯N, C—H⋯O and C—H⋯Br type, leading to a three-dimensional cross-linking of molecules. The pattern of non-covalent intermolecular bonding is completed by O⋯Br halogen bonds [3.306 (3) Å], which link the receptor molecules into infinite strands extending along the a-axis direction. International Union of Crystallography 2014-03-05 /pmc/articles/PMC3998546/ /pubmed/24826115 http://dx.doi.org/10.1107/S1600536814004383 Text en © Koch et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Koch, Niklas Seichter, Wilhelm Mazik, Monika 2-{2,4,6-Tris(bromomethyl)-3,5-bis[(1,3-dioxoisoindolin-2-yl)methyl]benzyl}isoindoline-1,3-dione toluene monosolvate |
title | 2-{2,4,6-Tris(bromomethyl)-3,5-bis[(1,3-dioxoisoindolin-2-yl)methyl]benzyl}isoindoline-1,3-dione toluene monosolvate |
title_full | 2-{2,4,6-Tris(bromomethyl)-3,5-bis[(1,3-dioxoisoindolin-2-yl)methyl]benzyl}isoindoline-1,3-dione toluene monosolvate |
title_fullStr | 2-{2,4,6-Tris(bromomethyl)-3,5-bis[(1,3-dioxoisoindolin-2-yl)methyl]benzyl}isoindoline-1,3-dione toluene monosolvate |
title_full_unstemmed | 2-{2,4,6-Tris(bromomethyl)-3,5-bis[(1,3-dioxoisoindolin-2-yl)methyl]benzyl}isoindoline-1,3-dione toluene monosolvate |
title_short | 2-{2,4,6-Tris(bromomethyl)-3,5-bis[(1,3-dioxoisoindolin-2-yl)methyl]benzyl}isoindoline-1,3-dione toluene monosolvate |
title_sort | 2-{2,4,6-tris(bromomethyl)-3,5-bis[(1,3-dioxoisoindolin-2-yl)methyl]benzyl}isoindoline-1,3-dione toluene monosolvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998546/ https://www.ncbi.nlm.nih.gov/pubmed/24826115 http://dx.doi.org/10.1107/S1600536814004383 |
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