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2-{2,4,6-Tris(bromo­meth­yl)-3,5-bis­[(1,3-dioxoisoindolin-2-yl)meth­yl]benz­yl}iso­indoline-1,3-dione toluene monosolvate

In the title compound, C(36)H(24)Br(3)N(3)O(6)·C(7)H(8), the toluene solvent mol­ecule is associated with the receptor mol­ecule via C—H⋯π bonding. The planes of the phthalimido groups are inclined at 77.0 (1), 63.0 (1) and 77.8 (1)° with respect to the benzene ring. The mol­ecular conformation is s...

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Detalles Bibliográficos
Autores principales: Koch, Niklas, Seichter, Wilhelm, Mazik, Monika
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998546/
https://www.ncbi.nlm.nih.gov/pubmed/24826115
http://dx.doi.org/10.1107/S1600536814004383
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author Koch, Niklas
Seichter, Wilhelm
Mazik, Monika
author_facet Koch, Niklas
Seichter, Wilhelm
Mazik, Monika
author_sort Koch, Niklas
collection PubMed
description In the title compound, C(36)H(24)Br(3)N(3)O(6)·C(7)H(8), the toluene solvent mol­ecule is associated with the receptor mol­ecule via C—H⋯π bonding. The planes of the phthalimido groups are inclined at 77.0 (1), 63.0 (1) and 77.8 (1)° with respect to the benzene ring. The mol­ecular conformation is stabilized by C—H⋯O and C—H⋯Br hydrogen bonds. The crystal structure features non-classical hydrogen bonds of the C—H⋯N, C—H⋯O and C—H⋯Br type, leading to a three-dimensional cross-linking of molecules. The pattern of non-covalent inter­molecular bonding is completed by O⋯Br halogen bonds [3.306 (3) Å], which link the receptor mol­ecules into infinite strands extending along the a-axis direction.
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spelling pubmed-39985462014-05-13 2-{2,4,6-Tris(bromo­meth­yl)-3,5-bis­[(1,3-dioxoisoindolin-2-yl)meth­yl]benz­yl}iso­indoline-1,3-dione toluene monosolvate Koch, Niklas Seichter, Wilhelm Mazik, Monika Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(36)H(24)Br(3)N(3)O(6)·C(7)H(8), the toluene solvent mol­ecule is associated with the receptor mol­ecule via C—H⋯π bonding. The planes of the phthalimido groups are inclined at 77.0 (1), 63.0 (1) and 77.8 (1)° with respect to the benzene ring. The mol­ecular conformation is stabilized by C—H⋯O and C—H⋯Br hydrogen bonds. The crystal structure features non-classical hydrogen bonds of the C—H⋯N, C—H⋯O and C—H⋯Br type, leading to a three-dimensional cross-linking of molecules. The pattern of non-covalent inter­molecular bonding is completed by O⋯Br halogen bonds [3.306 (3) Å], which link the receptor mol­ecules into infinite strands extending along the a-axis direction. International Union of Crystallography 2014-03-05 /pmc/articles/PMC3998546/ /pubmed/24826115 http://dx.doi.org/10.1107/S1600536814004383 Text en © Koch et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Koch, Niklas
Seichter, Wilhelm
Mazik, Monika
2-{2,4,6-Tris(bromo­meth­yl)-3,5-bis­[(1,3-dioxoisoindolin-2-yl)meth­yl]benz­yl}iso­indoline-1,3-dione toluene monosolvate
title 2-{2,4,6-Tris(bromo­meth­yl)-3,5-bis­[(1,3-dioxoisoindolin-2-yl)meth­yl]benz­yl}iso­indoline-1,3-dione toluene monosolvate
title_full 2-{2,4,6-Tris(bromo­meth­yl)-3,5-bis­[(1,3-dioxoisoindolin-2-yl)meth­yl]benz­yl}iso­indoline-1,3-dione toluene monosolvate
title_fullStr 2-{2,4,6-Tris(bromo­meth­yl)-3,5-bis­[(1,3-dioxoisoindolin-2-yl)meth­yl]benz­yl}iso­indoline-1,3-dione toluene monosolvate
title_full_unstemmed 2-{2,4,6-Tris(bromo­meth­yl)-3,5-bis­[(1,3-dioxoisoindolin-2-yl)meth­yl]benz­yl}iso­indoline-1,3-dione toluene monosolvate
title_short 2-{2,4,6-Tris(bromo­meth­yl)-3,5-bis­[(1,3-dioxoisoindolin-2-yl)meth­yl]benz­yl}iso­indoline-1,3-dione toluene monosolvate
title_sort 2-{2,4,6-tris(bromo­meth­yl)-3,5-bis­[(1,3-dioxoisoindolin-2-yl)meth­yl]benz­yl}iso­indoline-1,3-dione toluene monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998546/
https://www.ncbi.nlm.nih.gov/pubmed/24826115
http://dx.doi.org/10.1107/S1600536814004383
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