Cargando…

5-Chloro-3-ethyl­sulfinyl-7-methyl-2-(4-methyl­phen­yl)-1-benzo­furan

In the title compound, C(18)H(17)ClO(2)S, the dihedral angle between the mean planes of the benzo­furan ring system and the methyl­phenyl ring is 14.50 (4)°. The centroid–centroid distances between the benzene and the methyl­phenyl rings are 3.827 (2) and 3.741 (2) Å, while the centroid–centroid dis...

Descripción completa

Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Lee, Uk
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998548/
https://www.ncbi.nlm.nih.gov/pubmed/24826157
http://dx.doi.org/10.1107/S1600536814005601
_version_ 1782313385035038720
author Choi, Hong Dae
Seo, Pil Ja
Lee, Uk
author_facet Choi, Hong Dae
Seo, Pil Ja
Lee, Uk
author_sort Choi, Hong Dae
collection PubMed
description In the title compound, C(18)H(17)ClO(2)S, the dihedral angle between the mean planes of the benzo­furan ring system and the methyl­phenyl ring is 14.50 (4)°. The centroid–centroid distances between the benzene and the methyl­phenyl rings are 3.827 (2) and 3.741 (2) Å, while the centroid–centroid distance between the furan and methyl­phenyl rings is 3.843 (2) Å. These distances indicate π–π inter­actions; on the other hand, the inter­planar angles between the benzene and methyl­phenyl rings, and between the furan and methyl­phenyl rings are 13.89 (4) and 15.53 (4)°, respectively. In the crystal, the mol­ecules stack along the a-axis direction.
format Online
Article
Text
id pubmed-3998548
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-39985482014-05-13 5-Chloro-3-ethyl­sulfinyl-7-methyl-2-(4-methyl­phen­yl)-1-benzo­furan Choi, Hong Dae Seo, Pil Ja Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(17)ClO(2)S, the dihedral angle between the mean planes of the benzo­furan ring system and the methyl­phenyl ring is 14.50 (4)°. The centroid–centroid distances between the benzene and the methyl­phenyl rings are 3.827 (2) and 3.741 (2) Å, while the centroid–centroid distance between the furan and methyl­phenyl rings is 3.843 (2) Å. These distances indicate π–π inter­actions; on the other hand, the inter­planar angles between the benzene and methyl­phenyl rings, and between the furan and methyl­phenyl rings are 13.89 (4) and 15.53 (4)°, respectively. In the crystal, the mol­ecules stack along the a-axis direction. International Union of Crystallography 2014-03-19 /pmc/articles/PMC3998548/ /pubmed/24826157 http://dx.doi.org/10.1107/S1600536814005601 Text en © Choi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Choi, Hong Dae
Seo, Pil Ja
Lee, Uk
5-Chloro-3-ethyl­sulfinyl-7-methyl-2-(4-methyl­phen­yl)-1-benzo­furan
title 5-Chloro-3-ethyl­sulfinyl-7-methyl-2-(4-methyl­phen­yl)-1-benzo­furan
title_full 5-Chloro-3-ethyl­sulfinyl-7-methyl-2-(4-methyl­phen­yl)-1-benzo­furan
title_fullStr 5-Chloro-3-ethyl­sulfinyl-7-methyl-2-(4-methyl­phen­yl)-1-benzo­furan
title_full_unstemmed 5-Chloro-3-ethyl­sulfinyl-7-methyl-2-(4-methyl­phen­yl)-1-benzo­furan
title_short 5-Chloro-3-ethyl­sulfinyl-7-methyl-2-(4-methyl­phen­yl)-1-benzo­furan
title_sort 5-chloro-3-ethyl­sulfinyl-7-methyl-2-(4-methyl­phen­yl)-1-benzo­furan
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998548/
https://www.ncbi.nlm.nih.gov/pubmed/24826157
http://dx.doi.org/10.1107/S1600536814005601
work_keys_str_mv AT choihongdae 5chloro3ethylsulfinyl7methyl24methylphenyl1benzofuran
AT seopilja 5chloro3ethylsulfinyl7methyl24methylphenyl1benzofuran
AT leeuk 5chloro3ethylsulfinyl7methyl24methylphenyl1benzofuran