{2-[(2-Hy­droxy­benzyl­idene)amino]-4,5,6,7-tetra­hydro-1-benzo­thio­phen-3-yl}(phen­yl)methanone

In the title compound, C(22)H(19)NO(2)S, the cyclo­hexene ring adopts a slightly distorted half-chair conformation. The dihedral angles between the mean planes of the thio­phene ring and the phenyl and 2-hy­droxy­phenyl rings are 70.4 (5) and 12.1 (9)°, respectively. The phenyl and 2-hy­droxy­phenyl...

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Autores principales: Kaur, Manpreet, Jasinski, Jerry P., Kavitha, Channappa N., Yathirajan, H.S., Byrappa, K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998550/
https://www.ncbi.nlm.nih.gov/pubmed/24826172
http://dx.doi.org/10.1107/S1600536814006199
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author Kaur, Manpreet
Jasinski, Jerry P.
Kavitha, Channappa N.
Yathirajan, H.S.
Byrappa, K.
author_facet Kaur, Manpreet
Jasinski, Jerry P.
Kavitha, Channappa N.
Yathirajan, H.S.
Byrappa, K.
author_sort Kaur, Manpreet
collection PubMed
description In the title compound, C(22)H(19)NO(2)S, the cyclo­hexene ring adopts a slightly distorted half-chair conformation. The dihedral angles between the mean planes of the thio­phene ring and the phenyl and 2-hy­droxy­phenyl rings are 70.4 (5) and 12.1 (9)°, respectively. The phenyl and 2-hy­droxy­phenyl rings are twisted with respect to one another by 81.0 (6)°. A short intra­molecular O—H⋯N hydrogen bond is observed. In the crystal, weak C—H⋯O inter­actions link the mol­ecules into zigzag chains diagonally along [100] .
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spelling pubmed-39985502014-05-13 {2-[(2-Hy­droxy­benzyl­idene)amino]-4,5,6,7-tetra­hydro-1-benzo­thio­phen-3-yl}(phen­yl)methanone Kaur, Manpreet Jasinski, Jerry P. Kavitha, Channappa N. Yathirajan, H.S. Byrappa, K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(19)NO(2)S, the cyclo­hexene ring adopts a slightly distorted half-chair conformation. The dihedral angles between the mean planes of the thio­phene ring and the phenyl and 2-hy­droxy­phenyl rings are 70.4 (5) and 12.1 (9)°, respectively. The phenyl and 2-hy­droxy­phenyl rings are twisted with respect to one another by 81.0 (6)°. A short intra­molecular O—H⋯N hydrogen bond is observed. In the crystal, weak C—H⋯O inter­actions link the mol­ecules into zigzag chains diagonally along [100] . International Union of Crystallography 2014-03-26 /pmc/articles/PMC3998550/ /pubmed/24826172 http://dx.doi.org/10.1107/S1600536814006199 Text en © Kaur et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kaur, Manpreet
Jasinski, Jerry P.
Kavitha, Channappa N.
Yathirajan, H.S.
Byrappa, K.
{2-[(2-Hy­droxy­benzyl­idene)amino]-4,5,6,7-tetra­hydro-1-benzo­thio­phen-3-yl}(phen­yl)methanone
title {2-[(2-Hy­droxy­benzyl­idene)amino]-4,5,6,7-tetra­hydro-1-benzo­thio­phen-3-yl}(phen­yl)methanone
title_full {2-[(2-Hy­droxy­benzyl­idene)amino]-4,5,6,7-tetra­hydro-1-benzo­thio­phen-3-yl}(phen­yl)methanone
title_fullStr {2-[(2-Hy­droxy­benzyl­idene)amino]-4,5,6,7-tetra­hydro-1-benzo­thio­phen-3-yl}(phen­yl)methanone
title_full_unstemmed {2-[(2-Hy­droxy­benzyl­idene)amino]-4,5,6,7-tetra­hydro-1-benzo­thio­phen-3-yl}(phen­yl)methanone
title_short {2-[(2-Hy­droxy­benzyl­idene)amino]-4,5,6,7-tetra­hydro-1-benzo­thio­phen-3-yl}(phen­yl)methanone
title_sort {2-[(2-hy­droxy­benzyl­idene)amino]-4,5,6,7-tetra­hydro-1-benzo­thio­phen-3-yl}(phen­yl)methanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998550/
https://www.ncbi.nlm.nih.gov/pubmed/24826172
http://dx.doi.org/10.1107/S1600536814006199
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