7-Iso­propyl­idene-N (2),N (3),N (5),N (6)-tetra­meth­oxy-N (2),N (3),N (5),N (6)-tetra­methylbi­cyclo­[2.2.1]hepta-2,5-diene-2,3,5,6-tetra­carboxamide

Although the mol­ecular structure of the title compound, C(22)H(32)N(4)O(8), displays a twofold symmetry of the mol­ecule including the meth­oxy and methyl substituents, no crystallographic twofold symmetry is observed in the X-ray structure analysis. The carbonyl O atoms alternately point to differ...

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Detalles Bibliográficos
Autores principales: Sahlmann, Benjamin, Näther, Christian, Herges, Rainer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998551/
https://www.ncbi.nlm.nih.gov/pubmed/24826143
http://dx.doi.org/10.1107/S1600536814004255
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author Sahlmann, Benjamin
Näther, Christian
Herges, Rainer
author_facet Sahlmann, Benjamin
Näther, Christian
Herges, Rainer
author_sort Sahlmann, Benjamin
collection PubMed
description Although the mol­ecular structure of the title compound, C(22)H(32)N(4)O(8), displays a twofold symmetry of the mol­ecule including the meth­oxy and methyl substituents, no crystallographic twofold symmetry is observed in the X-ray structure analysis. The carbonyl O atoms alternately point to different sides of the plane defined by the carbonyl C atoms. Two meth­oxy groups are oriented inside the mol­ecules cavity. The H atoms of two methyl groups are disordered over two orientations and were refined using a split model.
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spelling pubmed-39985512014-05-13 7-Iso­propyl­idene-N (2),N (3),N (5),N (6)-tetra­meth­oxy-N (2),N (3),N (5),N (6)-tetra­methylbi­cyclo­[2.2.1]hepta-2,5-diene-2,3,5,6-tetra­carboxamide Sahlmann, Benjamin Näther, Christian Herges, Rainer Acta Crystallogr Sect E Struct Rep Online Organic Papers Although the mol­ecular structure of the title compound, C(22)H(32)N(4)O(8), displays a twofold symmetry of the mol­ecule including the meth­oxy and methyl substituents, no crystallographic twofold symmetry is observed in the X-ray structure analysis. The carbonyl O atoms alternately point to different sides of the plane defined by the carbonyl C atoms. Two meth­oxy groups are oriented inside the mol­ecules cavity. The H atoms of two methyl groups are disordered over two orientations and were refined using a split model. International Union of Crystallography 2014-03-15 /pmc/articles/PMC3998551/ /pubmed/24826143 http://dx.doi.org/10.1107/S1600536814004255 Text en © Sahlmann et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sahlmann, Benjamin
Näther, Christian
Herges, Rainer
7-Iso­propyl­idene-N (2),N (3),N (5),N (6)-tetra­meth­oxy-N (2),N (3),N (5),N (6)-tetra­methylbi­cyclo­[2.2.1]hepta-2,5-diene-2,3,5,6-tetra­carboxamide
title 7-Iso­propyl­idene-N (2),N (3),N (5),N (6)-tetra­meth­oxy-N (2),N (3),N (5),N (6)-tetra­methylbi­cyclo­[2.2.1]hepta-2,5-diene-2,3,5,6-tetra­carboxamide
title_full 7-Iso­propyl­idene-N (2),N (3),N (5),N (6)-tetra­meth­oxy-N (2),N (3),N (5),N (6)-tetra­methylbi­cyclo­[2.2.1]hepta-2,5-diene-2,3,5,6-tetra­carboxamide
title_fullStr 7-Iso­propyl­idene-N (2),N (3),N (5),N (6)-tetra­meth­oxy-N (2),N (3),N (5),N (6)-tetra­methylbi­cyclo­[2.2.1]hepta-2,5-diene-2,3,5,6-tetra­carboxamide
title_full_unstemmed 7-Iso­propyl­idene-N (2),N (3),N (5),N (6)-tetra­meth­oxy-N (2),N (3),N (5),N (6)-tetra­methylbi­cyclo­[2.2.1]hepta-2,5-diene-2,3,5,6-tetra­carboxamide
title_short 7-Iso­propyl­idene-N (2),N (3),N (5),N (6)-tetra­meth­oxy-N (2),N (3),N (5),N (6)-tetra­methylbi­cyclo­[2.2.1]hepta-2,5-diene-2,3,5,6-tetra­carboxamide
title_sort 7-iso­propyl­idene-n (2),n (3),n (5),n (6)-tetra­meth­oxy-n (2),n (3),n (5),n (6)-tetra­methylbi­cyclo­[2.2.1]hepta-2,5-diene-2,3,5,6-tetra­carboxamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998551/
https://www.ncbi.nlm.nih.gov/pubmed/24826143
http://dx.doi.org/10.1107/S1600536814004255
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