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(4-Methylpiperazin-1-yl)(2,3,4-trimethoxybenzylidene)amine
In the title compound, C(15)H(23)N(3)O(3), the piperazine ring is in a slightly distorted chair conformation and is twisted from the mean plane of the benzene ring making a dihedral angle of 14.94 (6)°. The 4-methoxy substituent is almost co-planar with the benzene ring [C—C—O—C torsion angle = 5.4...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998554/ https://www.ncbi.nlm.nih.gov/pubmed/24826188 http://dx.doi.org/10.1107/S1600536814006291 |
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author | Kavitha, Channappa N. Jasinski, Jerry P. Kaur, Manpreet Yathirajan, H.S. |
author_facet | Kavitha, Channappa N. Jasinski, Jerry P. Kaur, Manpreet Yathirajan, H.S. |
author_sort | Kavitha, Channappa N. |
collection | PubMed |
description | In the title compound, C(15)H(23)N(3)O(3), the piperazine ring is in a slightly distorted chair conformation and is twisted from the mean plane of the benzene ring making a dihedral angle of 14.94 (6)°. The 4-methoxy substituent is almost co-planar with the benzene ring [C—C—O—C torsion angle = 5.4 (1)°], while the methoxy groups at positions 2 and 3 [C—C—O—C torsion angles of 122.6 (4) and −66.1 (4)°, respectively] are twisted away from the mean plane of the benzene ring in anticlinical and synclinical conformations, respectively. No classical hydrogen bonds or any weak intermolecular interactions are observed in the crystal structure. |
format | Online Article Text |
id | pubmed-3998554 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39985542014-05-13 (4-Methylpiperazin-1-yl)(2,3,4-trimethoxybenzylidene)amine Kavitha, Channappa N. Jasinski, Jerry P. Kaur, Manpreet Yathirajan, H.S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(23)N(3)O(3), the piperazine ring is in a slightly distorted chair conformation and is twisted from the mean plane of the benzene ring making a dihedral angle of 14.94 (6)°. The 4-methoxy substituent is almost co-planar with the benzene ring [C—C—O—C torsion angle = 5.4 (1)°], while the methoxy groups at positions 2 and 3 [C—C—O—C torsion angles of 122.6 (4) and −66.1 (4)°, respectively] are twisted away from the mean plane of the benzene ring in anticlinical and synclinical conformations, respectively. No classical hydrogen bonds or any weak intermolecular interactions are observed in the crystal structure. International Union of Crystallography 2014-03-29 /pmc/articles/PMC3998554/ /pubmed/24826188 http://dx.doi.org/10.1107/S1600536814006291 Text en © Kavitha et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kavitha, Channappa N. Jasinski, Jerry P. Kaur, Manpreet Yathirajan, H.S. (4-Methylpiperazin-1-yl)(2,3,4-trimethoxybenzylidene)amine |
title | (4-Methylpiperazin-1-yl)(2,3,4-trimethoxybenzylidene)amine |
title_full | (4-Methylpiperazin-1-yl)(2,3,4-trimethoxybenzylidene)amine |
title_fullStr | (4-Methylpiperazin-1-yl)(2,3,4-trimethoxybenzylidene)amine |
title_full_unstemmed | (4-Methylpiperazin-1-yl)(2,3,4-trimethoxybenzylidene)amine |
title_short | (4-Methylpiperazin-1-yl)(2,3,4-trimethoxybenzylidene)amine |
title_sort | (4-methylpiperazin-1-yl)(2,3,4-trimethoxybenzylidene)amine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998554/ https://www.ncbi.nlm.nih.gov/pubmed/24826188 http://dx.doi.org/10.1107/S1600536814006291 |
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