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(4-Methyl­piperazin-1-yl)(2,3,4-tri­meth­oxy­benzyl­idene)amine

In the title compound, C(15)H(23)N(3)O(3), the piperazine ring is in a slightly distorted chair conformation and is twisted from the mean plane of the benzene ring making a dihedral angle of 14.94 (6)°. The 4-meth­oxy substituent is almost co-planar with the benzene ring [C—C—O—C torsion angle = 5.4...

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Autores principales: Kavitha, Channappa N., Jasinski, Jerry P., Kaur, Manpreet, Yathirajan, H.S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998554/
https://www.ncbi.nlm.nih.gov/pubmed/24826188
http://dx.doi.org/10.1107/S1600536814006291
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author Kavitha, Channappa N.
Jasinski, Jerry P.
Kaur, Manpreet
Yathirajan, H.S.
author_facet Kavitha, Channappa N.
Jasinski, Jerry P.
Kaur, Manpreet
Yathirajan, H.S.
author_sort Kavitha, Channappa N.
collection PubMed
description In the title compound, C(15)H(23)N(3)O(3), the piperazine ring is in a slightly distorted chair conformation and is twisted from the mean plane of the benzene ring making a dihedral angle of 14.94 (6)°. The 4-meth­oxy substituent is almost co-planar with the benzene ring [C—C—O—C torsion angle = 5.4 (1)°], while the meth­oxy groups at positions 2 and 3 [C—C—O—C torsion angles of 122.6 (4) and −66.1 (4)°, respectively] are twisted away from the mean plane of the benzene ring in anti­clinical and synclinical conformations, respectively. No classical hydrogen bonds or any weak inter­molecular inter­actions are observed in the crystal structure.
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spelling pubmed-39985542014-05-13 (4-Methyl­piperazin-1-yl)(2,3,4-tri­meth­oxy­benzyl­idene)amine Kavitha, Channappa N. Jasinski, Jerry P. Kaur, Manpreet Yathirajan, H.S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(23)N(3)O(3), the piperazine ring is in a slightly distorted chair conformation and is twisted from the mean plane of the benzene ring making a dihedral angle of 14.94 (6)°. The 4-meth­oxy substituent is almost co-planar with the benzene ring [C—C—O—C torsion angle = 5.4 (1)°], while the meth­oxy groups at positions 2 and 3 [C—C—O—C torsion angles of 122.6 (4) and −66.1 (4)°, respectively] are twisted away from the mean plane of the benzene ring in anti­clinical and synclinical conformations, respectively. No classical hydrogen bonds or any weak inter­molecular inter­actions are observed in the crystal structure. International Union of Crystallography 2014-03-29 /pmc/articles/PMC3998554/ /pubmed/24826188 http://dx.doi.org/10.1107/S1600536814006291 Text en © Kavitha et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kavitha, Channappa N.
Jasinski, Jerry P.
Kaur, Manpreet
Yathirajan, H.S.
(4-Methyl­piperazin-1-yl)(2,3,4-tri­meth­oxy­benzyl­idene)amine
title (4-Methyl­piperazin-1-yl)(2,3,4-tri­meth­oxy­benzyl­idene)amine
title_full (4-Methyl­piperazin-1-yl)(2,3,4-tri­meth­oxy­benzyl­idene)amine
title_fullStr (4-Methyl­piperazin-1-yl)(2,3,4-tri­meth­oxy­benzyl­idene)amine
title_full_unstemmed (4-Methyl­piperazin-1-yl)(2,3,4-tri­meth­oxy­benzyl­idene)amine
title_short (4-Methyl­piperazin-1-yl)(2,3,4-tri­meth­oxy­benzyl­idene)amine
title_sort (4-methyl­piperazin-1-yl)(2,3,4-tri­meth­oxy­benzyl­idene)amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998554/
https://www.ncbi.nlm.nih.gov/pubmed/24826188
http://dx.doi.org/10.1107/S1600536814006291
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