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2-(4,5-Dimethoxy-2-nitrophenyl)-4-methoxy-9-phenylsulfonyl-9H-carbazole-3-carbaldehyde
In the title compound, C(28)H(22)N(2)O(8)S, the carbazole ring system is roughly planar, with a maximum deviation of 0.084 (3) Å for the C atom connected to the 4,5-dimethoxy-2-nitrophenyl ring. The dihedral angle between the carbazole system and the dimethoxy-substituted nitrophenyl ring is 57....
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998565/ https://www.ncbi.nlm.nih.gov/pubmed/24826135 http://dx.doi.org/10.1107/S1600536814005133 |
Sumario: | In the title compound, C(28)H(22)N(2)O(8)S, the carbazole ring system is roughly planar, with a maximum deviation of 0.084 (3) Å for the C atom connected to the 4,5-dimethoxy-2-nitrophenyl ring. The dihedral angle between the carbazole system and the dimethoxy-substituted nitrophenyl ring is 57.05 (10)°. The aldehyde C atom deviates by 0.164 (5) Å from its attached carbazole ring system. The molecular structure is stabilized by C—H⋯O interactions which generate two S(6) and one S(7) ring motif. In the crystal, molecules are linked by C—H⋯O hydrogen bonds, forming R (3) (3)(15) ring motifs, which are further crosslinked by R (3) (2)(19) ring motifs, resulting in (002) layers. The crystal packing also features C—H⋯π interactions. |
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