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2-(4,5-Dimeth­oxy-2-nitro­phen­yl)-4-meth­oxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde

In the title compound, C(28)H(22)N(2)O(8)S, the carbazole ring system is roughly planar, with a maximum deviation of 0.084 (3) Å for the C atom connected to the 4,5-dimeth­oxy-2-nitro­phenyl ring. The dihedral angle between the carbazole system and the dimeth­oxy-substituted nitro­phenyl ring is 57....

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Autores principales: Narayanan, P., Sethusankar, K., Saravanan, Velu, Mohanakrishnan, Arasambattu K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998565/
https://www.ncbi.nlm.nih.gov/pubmed/24826135
http://dx.doi.org/10.1107/S1600536814005133
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author Narayanan, P.
Sethusankar, K.
Saravanan, Velu
Mohanakrishnan, Arasambattu K.
author_facet Narayanan, P.
Sethusankar, K.
Saravanan, Velu
Mohanakrishnan, Arasambattu K.
author_sort Narayanan, P.
collection PubMed
description In the title compound, C(28)H(22)N(2)O(8)S, the carbazole ring system is roughly planar, with a maximum deviation of 0.084 (3) Å for the C atom connected to the 4,5-dimeth­oxy-2-nitro­phenyl ring. The dihedral angle between the carbazole system and the dimeth­oxy-substituted nitro­phenyl ring is 57.05 (10)°. The aldehyde C atom deviates by 0.164 (5) Å from its attached carbazole ring system. The mol­ecular structure is stabilized by C—H⋯O inter­actions which generate two S(6) and one S(7) ring motif. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, forming R (3) (3)(15) ring motifs, which are further crosslinked by R (3) (2)(19) ring motifs, resulting in (002) layers. The crystal packing also features C—H⋯π inter­actions.
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spelling pubmed-39985652014-05-13 2-(4,5-Dimeth­oxy-2-nitro­phen­yl)-4-meth­oxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde Narayanan, P. Sethusankar, K. Saravanan, Velu Mohanakrishnan, Arasambattu K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(28)H(22)N(2)O(8)S, the carbazole ring system is roughly planar, with a maximum deviation of 0.084 (3) Å for the C atom connected to the 4,5-dimeth­oxy-2-nitro­phenyl ring. The dihedral angle between the carbazole system and the dimeth­oxy-substituted nitro­phenyl ring is 57.05 (10)°. The aldehyde C atom deviates by 0.164 (5) Å from its attached carbazole ring system. The mol­ecular structure is stabilized by C—H⋯O inter­actions which generate two S(6) and one S(7) ring motif. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, forming R (3) (3)(15) ring motifs, which are further crosslinked by R (3) (2)(19) ring motifs, resulting in (002) layers. The crystal packing also features C—H⋯π inter­actions. International Union of Crystallography 2014-03-12 /pmc/articles/PMC3998565/ /pubmed/24826135 http://dx.doi.org/10.1107/S1600536814005133 Text en © Narayanan et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Narayanan, P.
Sethusankar, K.
Saravanan, Velu
Mohanakrishnan, Arasambattu K.
2-(4,5-Dimeth­oxy-2-nitro­phen­yl)-4-meth­oxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title 2-(4,5-Dimeth­oxy-2-nitro­phen­yl)-4-meth­oxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_full 2-(4,5-Dimeth­oxy-2-nitro­phen­yl)-4-meth­oxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_fullStr 2-(4,5-Dimeth­oxy-2-nitro­phen­yl)-4-meth­oxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_full_unstemmed 2-(4,5-Dimeth­oxy-2-nitro­phen­yl)-4-meth­oxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_short 2-(4,5-Dimeth­oxy-2-nitro­phen­yl)-4-meth­oxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_sort 2-(4,5-dimeth­oxy-2-nitro­phen­yl)-4-meth­oxy-9-phenyl­sulfonyl-9h-carbazole-3-carbaldehyde
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998565/
https://www.ncbi.nlm.nih.gov/pubmed/24826135
http://dx.doi.org/10.1107/S1600536814005133
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