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2-(4,5-Dimethoxy-2-nitrophenyl)-4-methoxy-9-phenylsulfonyl-9H-carbazole-3-carbaldehyde
In the title compound, C(28)H(22)N(2)O(8)S, the carbazole ring system is roughly planar, with a maximum deviation of 0.084 (3) Å for the C atom connected to the 4,5-dimethoxy-2-nitrophenyl ring. The dihedral angle between the carbazole system and the dimethoxy-substituted nitrophenyl ring is 57....
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998565/ https://www.ncbi.nlm.nih.gov/pubmed/24826135 http://dx.doi.org/10.1107/S1600536814005133 |
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author | Narayanan, P. Sethusankar, K. Saravanan, Velu Mohanakrishnan, Arasambattu K. |
author_facet | Narayanan, P. Sethusankar, K. Saravanan, Velu Mohanakrishnan, Arasambattu K. |
author_sort | Narayanan, P. |
collection | PubMed |
description | In the title compound, C(28)H(22)N(2)O(8)S, the carbazole ring system is roughly planar, with a maximum deviation of 0.084 (3) Å for the C atom connected to the 4,5-dimethoxy-2-nitrophenyl ring. The dihedral angle between the carbazole system and the dimethoxy-substituted nitrophenyl ring is 57.05 (10)°. The aldehyde C atom deviates by 0.164 (5) Å from its attached carbazole ring system. The molecular structure is stabilized by C—H⋯O interactions which generate two S(6) and one S(7) ring motif. In the crystal, molecules are linked by C—H⋯O hydrogen bonds, forming R (3) (3)(15) ring motifs, which are further crosslinked by R (3) (2)(19) ring motifs, resulting in (002) layers. The crystal packing also features C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3998565 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39985652014-05-13 2-(4,5-Dimethoxy-2-nitrophenyl)-4-methoxy-9-phenylsulfonyl-9H-carbazole-3-carbaldehyde Narayanan, P. Sethusankar, K. Saravanan, Velu Mohanakrishnan, Arasambattu K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(28)H(22)N(2)O(8)S, the carbazole ring system is roughly planar, with a maximum deviation of 0.084 (3) Å for the C atom connected to the 4,5-dimethoxy-2-nitrophenyl ring. The dihedral angle between the carbazole system and the dimethoxy-substituted nitrophenyl ring is 57.05 (10)°. The aldehyde C atom deviates by 0.164 (5) Å from its attached carbazole ring system. The molecular structure is stabilized by C—H⋯O interactions which generate two S(6) and one S(7) ring motif. In the crystal, molecules are linked by C—H⋯O hydrogen bonds, forming R (3) (3)(15) ring motifs, which are further crosslinked by R (3) (2)(19) ring motifs, resulting in (002) layers. The crystal packing also features C—H⋯π interactions. International Union of Crystallography 2014-03-12 /pmc/articles/PMC3998565/ /pubmed/24826135 http://dx.doi.org/10.1107/S1600536814005133 Text en © Narayanan et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Narayanan, P. Sethusankar, K. Saravanan, Velu Mohanakrishnan, Arasambattu K. 2-(4,5-Dimethoxy-2-nitrophenyl)-4-methoxy-9-phenylsulfonyl-9H-carbazole-3-carbaldehyde |
title | 2-(4,5-Dimethoxy-2-nitrophenyl)-4-methoxy-9-phenylsulfonyl-9H-carbazole-3-carbaldehyde |
title_full | 2-(4,5-Dimethoxy-2-nitrophenyl)-4-methoxy-9-phenylsulfonyl-9H-carbazole-3-carbaldehyde |
title_fullStr | 2-(4,5-Dimethoxy-2-nitrophenyl)-4-methoxy-9-phenylsulfonyl-9H-carbazole-3-carbaldehyde |
title_full_unstemmed | 2-(4,5-Dimethoxy-2-nitrophenyl)-4-methoxy-9-phenylsulfonyl-9H-carbazole-3-carbaldehyde |
title_short | 2-(4,5-Dimethoxy-2-nitrophenyl)-4-methoxy-9-phenylsulfonyl-9H-carbazole-3-carbaldehyde |
title_sort | 2-(4,5-dimethoxy-2-nitrophenyl)-4-methoxy-9-phenylsulfonyl-9h-carbazole-3-carbaldehyde |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998565/ https://www.ncbi.nlm.nih.gov/pubmed/24826135 http://dx.doi.org/10.1107/S1600536814005133 |
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