Glycinium 3-carb­oxy-4-hy­droxy­benzene­sulfonate

In the anion of the title salt, C(2)H(6)NO(2) (+)·C(7)H(5)O(6)S(−), the dihedral angle between the carb­oxy­lic acid group and the benzene ring is 5.02 (12)°. In the crystal, the anions are linked into inversion dimers through pairs of O—H⋯O hydrogen bonds between the carb­oxy­lic acid groups and su...

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Autores principales: Thirunavukkarasu, A., Silambarasan, A., Kumar, R. Mohan, Umarani, P. R., Chakkaravarthi, G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998566/
https://www.ncbi.nlm.nih.gov/pubmed/24826117
http://dx.doi.org/10.1107/S1600536814004590
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author Thirunavukkarasu, A.
Silambarasan, A.
Kumar, R. Mohan
Umarani, P. R.
Chakkaravarthi, G.
author_facet Thirunavukkarasu, A.
Silambarasan, A.
Kumar, R. Mohan
Umarani, P. R.
Chakkaravarthi, G.
author_sort Thirunavukkarasu, A.
collection PubMed
description In the anion of the title salt, C(2)H(6)NO(2) (+)·C(7)H(5)O(6)S(−), the dihedral angle between the carb­oxy­lic acid group and the benzene ring is 5.02 (12)°. In the crystal, the anions are linked into inversion dimers through pairs of O—H⋯O hydrogen bonds between the carb­oxy­lic acid groups and sulfonate O atoms. A pair of C—H⋯O inter­actions is also observed within each dimer. The anion dimers and the cations are linked into a three-dimensional network by N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds.
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spelling pubmed-39985662014-05-13 Glycinium 3-carb­oxy-4-hy­droxy­benzene­sulfonate Thirunavukkarasu, A. Silambarasan, A. Kumar, R. Mohan Umarani, P. R. Chakkaravarthi, G. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the anion of the title salt, C(2)H(6)NO(2) (+)·C(7)H(5)O(6)S(−), the dihedral angle between the carb­oxy­lic acid group and the benzene ring is 5.02 (12)°. In the crystal, the anions are linked into inversion dimers through pairs of O—H⋯O hydrogen bonds between the carb­oxy­lic acid groups and sulfonate O atoms. A pair of C—H⋯O inter­actions is also observed within each dimer. The anion dimers and the cations are linked into a three-dimensional network by N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds. International Union of Crystallography 2014-03-05 /pmc/articles/PMC3998566/ /pubmed/24826117 http://dx.doi.org/10.1107/S1600536814004590 Text en © Thirunavukkarasu et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Thirunavukkarasu, A.
Silambarasan, A.
Kumar, R. Mohan
Umarani, P. R.
Chakkaravarthi, G.
Glycinium 3-carb­oxy-4-hy­droxy­benzene­sulfonate
title Glycinium 3-carb­oxy-4-hy­droxy­benzene­sulfonate
title_full Glycinium 3-carb­oxy-4-hy­droxy­benzene­sulfonate
title_fullStr Glycinium 3-carb­oxy-4-hy­droxy­benzene­sulfonate
title_full_unstemmed Glycinium 3-carb­oxy-4-hy­droxy­benzene­sulfonate
title_short Glycinium 3-carb­oxy-4-hy­droxy­benzene­sulfonate
title_sort glycinium 3-carb­oxy-4-hy­droxy­benzene­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998566/
https://www.ncbi.nlm.nih.gov/pubmed/24826117
http://dx.doi.org/10.1107/S1600536814004590
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AT kumarrmohan glycinium3carboxy4hydroxybenzenesulfonate
AT umaranipr glycinium3carboxy4hydroxybenzenesulfonate
AT chakkaravarthig glycinium3carboxy4hydroxybenzenesulfonate

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