Bis(N-nitroso-N-pentyl­hydroxy­laminato-κ(2) O,O′)copper(II)

In the centrosymmetric title compound, [Cu(C(5)H(11)N(2)O(2))(2)], the Cu(2+) ion, located on an inversion centre (Wyckoff position 2b), is in a square-planar environment, surounded by four O atoms of the N—O groups of two N-nitroso-N-pentyl­hydroxy­laminate ligands [Cu—O = 1.9042 (17) and 1.9095 (1...

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Detalles Bibliográficos
Autores principales: Sheikh Bostanabad, Ali, Kovalchukova, Olga, Strashnova, Svetlana, Stash, Adam, Zyuzin, Igor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998568/
https://www.ncbi.nlm.nih.gov/pubmed/24826099
http://dx.doi.org/10.1107/S1600536814004978
Descripción
Sumario:In the centrosymmetric title compound, [Cu(C(5)H(11)N(2)O(2))(2)], the Cu(2+) ion, located on an inversion centre (Wyckoff position 2b), is in a square-planar environment, surounded by four O atoms of the N—O groups of two N-nitroso-N-pentyl­hydroxy­laminate ligands [Cu—O = 1.9042 (17) and 1.9095 (16) Å]. The hy­droxy­laminate monoanions are bidentate chelating ligands. The Cu(2+) cations form stacks along [010], with inter­molecular Cu⋯N contacts of 3.146 (2) and 3.653 (2) Å.

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