Bis(N-nitroso-N-pentyl­hydroxy­laminato-κ(2) O,O′)copper(II)

In the centrosymmetric title compound, [Cu(C(5)H(11)N(2)O(2))(2)], the Cu(2+) ion, located on an inversion centre (Wyckoff position 2b), is in a square-planar environment, surounded by four O atoms of the N—O groups of two N-nitroso-N-pentyl­hydroxy­laminate ligands [Cu—O = 1.9042 (17) and 1.9095 (1...

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Autores principales: Sheikh Bostanabad, Ali, Kovalchukova, Olga, Strashnova, Svetlana, Stash, Adam, Zyuzin, Igor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998568/
https://www.ncbi.nlm.nih.gov/pubmed/24826099
http://dx.doi.org/10.1107/S1600536814004978
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author Sheikh Bostanabad, Ali
Kovalchukova, Olga
Strashnova, Svetlana
Stash, Adam
Zyuzin, Igor
author_facet Sheikh Bostanabad, Ali
Kovalchukova, Olga
Strashnova, Svetlana
Stash, Adam
Zyuzin, Igor
author_sort Sheikh Bostanabad, Ali
collection PubMed
description In the centrosymmetric title compound, [Cu(C(5)H(11)N(2)O(2))(2)], the Cu(2+) ion, located on an inversion centre (Wyckoff position 2b), is in a square-planar environment, surounded by four O atoms of the N—O groups of two N-nitroso-N-pentyl­hydroxy­laminate ligands [Cu—O = 1.9042 (17) and 1.9095 (16) Å]. The hy­droxy­laminate monoanions are bidentate chelating ligands. The Cu(2+) cations form stacks along [010], with inter­molecular Cu⋯N contacts of 3.146 (2) and 3.653 (2) Å.
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spelling pubmed-39985682014-05-13 Bis(N-nitroso-N-pentyl­hydroxy­laminato-κ(2) O,O′)copper(II) Sheikh Bostanabad, Ali Kovalchukova, Olga Strashnova, Svetlana Stash, Adam Zyuzin, Igor Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title compound, [Cu(C(5)H(11)N(2)O(2))(2)], the Cu(2+) ion, located on an inversion centre (Wyckoff position 2b), is in a square-planar environment, surounded by four O atoms of the N—O groups of two N-nitroso-N-pentyl­hydroxy­laminate ligands [Cu—O = 1.9042 (17) and 1.9095 (16) Å]. The hy­droxy­laminate monoanions are bidentate chelating ligands. The Cu(2+) cations form stacks along [010], with inter­molecular Cu⋯N contacts of 3.146 (2) and 3.653 (2) Å. International Union of Crystallography 2014-03-19 /pmc/articles/PMC3998568/ /pubmed/24826099 http://dx.doi.org/10.1107/S1600536814004978 Text en © Sheikh Bostanabad et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sheikh Bostanabad, Ali
Kovalchukova, Olga
Strashnova, Svetlana
Stash, Adam
Zyuzin, Igor
Bis(N-nitroso-N-pentyl­hydroxy­laminato-κ(2) O,O′)copper(II)
title Bis(N-nitroso-N-pentyl­hydroxy­laminato-κ(2) O,O′)copper(II)
title_full Bis(N-nitroso-N-pentyl­hydroxy­laminato-κ(2) O,O′)copper(II)
title_fullStr Bis(N-nitroso-N-pentyl­hydroxy­laminato-κ(2) O,O′)copper(II)
title_full_unstemmed Bis(N-nitroso-N-pentyl­hydroxy­laminato-κ(2) O,O′)copper(II)
title_short Bis(N-nitroso-N-pentyl­hydroxy­laminato-κ(2) O,O′)copper(II)
title_sort bis(n-nitroso-n-pentyl­hydroxy­laminato-κ(2) o,o′)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998568/
https://www.ncbi.nlm.nih.gov/pubmed/24826099
http://dx.doi.org/10.1107/S1600536814004978
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