(1S*,3R*,5S*,7S*)-4,4,8,8-Tetra­chloro-1-isopropyl-5-methyl­tri­cyclo­[5.1.0.0(3,5)]octa­ne

The title compound, C(12)H(16)Cl(4), is a derivative of the natural product 1-isopropyl-4-methyl­cyclo­hexa-1,4-diene, and represents a diastereomer with two trans-fused cyclo­propane rings. Both enanti­omers are present in the non-centrosymmetric polar space group Pna2(1). The central cyclo­hexane...

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Detalles Bibliográficos
Autores principales: Turdybekov, Koblandy M., Ryazantsev, Oleg G., Atazhanova, Gayane A., Adekenov, Sergazy M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998570/
https://www.ncbi.nlm.nih.gov/pubmed/24826130
http://dx.doi.org/10.1107/S1600536814004826
Descripción
Sumario:The title compound, C(12)H(16)Cl(4), is a derivative of the natural product 1-isopropyl-4-methyl­cyclo­hexa-1,4-diene, and represents a diastereomer with two trans-fused cyclo­propane rings. Both enanti­omers are present in the non-centrosymmetric polar space group Pna2(1). The central cyclo­hexane ring is planar within 0.02 (1) Å. The C atoms of di­chloro­methyl­ene groups deviate from this plane by 1.19 (1) and −1.26 (1) Å, whereas the isopropyl and methyl groups are oriented more equatorially, deviating by 0.71 (1) and −0.87 (1) Å, respectively.

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