(1S*,3R*,5S*,7S*)-4,4,8,8-Tetra­chloro-1-isopropyl-5-methyl­tri­cyclo­[5.1.0.0(3,5)]octa­ne

The title compound, C(12)H(16)Cl(4), is a derivative of the natural product 1-isopropyl-4-methyl­cyclo­hexa-1,4-diene, and represents a diastereomer with two trans-fused cyclo­propane rings. Both enanti­omers are present in the non-centrosymmetric polar space group Pna2(1). The central cyclo­hexane...

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Autores principales: Turdybekov, Koblandy M., Ryazantsev, Oleg G., Atazhanova, Gayane A., Adekenov, Sergazy M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998570/
https://www.ncbi.nlm.nih.gov/pubmed/24826130
http://dx.doi.org/10.1107/S1600536814004826
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author Turdybekov, Koblandy M.
Ryazantsev, Oleg G.
Atazhanova, Gayane A.
Adekenov, Sergazy M.
author_facet Turdybekov, Koblandy M.
Ryazantsev, Oleg G.
Atazhanova, Gayane A.
Adekenov, Sergazy M.
author_sort Turdybekov, Koblandy M.
collection PubMed
description The title compound, C(12)H(16)Cl(4), is a derivative of the natural product 1-isopropyl-4-methyl­cyclo­hexa-1,4-diene, and represents a diastereomer with two trans-fused cyclo­propane rings. Both enanti­omers are present in the non-centrosymmetric polar space group Pna2(1). The central cyclo­hexane ring is planar within 0.02 (1) Å. The C atoms of di­chloro­methyl­ene groups deviate from this plane by 1.19 (1) and −1.26 (1) Å, whereas the isopropyl and methyl groups are oriented more equatorially, deviating by 0.71 (1) and −0.87 (1) Å, respectively.
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spelling pubmed-39985702014-05-13 (1S*,3R*,5S*,7S*)-4,4,8,8-Tetra­chloro-1-isopropyl-5-methyl­tri­cyclo­[5.1.0.0(3,5)]octa­ne Turdybekov, Koblandy M. Ryazantsev, Oleg G. Atazhanova, Gayane A. Adekenov, Sergazy M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(12)H(16)Cl(4), is a derivative of the natural product 1-isopropyl-4-methyl­cyclo­hexa-1,4-diene, and represents a diastereomer with two trans-fused cyclo­propane rings. Both enanti­omers are present in the non-centrosymmetric polar space group Pna2(1). The central cyclo­hexane ring is planar within 0.02 (1) Å. The C atoms of di­chloro­methyl­ene groups deviate from this plane by 1.19 (1) and −1.26 (1) Å, whereas the isopropyl and methyl groups are oriented more equatorially, deviating by 0.71 (1) and −0.87 (1) Å, respectively. International Union of Crystallography 2014-03-12 /pmc/articles/PMC3998570/ /pubmed/24826130 http://dx.doi.org/10.1107/S1600536814004826 Text en © Turdybekov et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Turdybekov, Koblandy M.
Ryazantsev, Oleg G.
Atazhanova, Gayane A.
Adekenov, Sergazy M.
(1S*,3R*,5S*,7S*)-4,4,8,8-Tetra­chloro-1-isopropyl-5-methyl­tri­cyclo­[5.1.0.0(3,5)]octa­ne
title (1S*,3R*,5S*,7S*)-4,4,8,8-Tetra­chloro-1-isopropyl-5-methyl­tri­cyclo­[5.1.0.0(3,5)]octa­ne
title_full (1S*,3R*,5S*,7S*)-4,4,8,8-Tetra­chloro-1-isopropyl-5-methyl­tri­cyclo­[5.1.0.0(3,5)]octa­ne
title_fullStr (1S*,3R*,5S*,7S*)-4,4,8,8-Tetra­chloro-1-isopropyl-5-methyl­tri­cyclo­[5.1.0.0(3,5)]octa­ne
title_full_unstemmed (1S*,3R*,5S*,7S*)-4,4,8,8-Tetra­chloro-1-isopropyl-5-methyl­tri­cyclo­[5.1.0.0(3,5)]octa­ne
title_short (1S*,3R*,5S*,7S*)-4,4,8,8-Tetra­chloro-1-isopropyl-5-methyl­tri­cyclo­[5.1.0.0(3,5)]octa­ne
title_sort (1s*,3r*,5s*,7s*)-4,4,8,8-tetra­chloro-1-isopropyl-5-methyl­tri­cyclo­[5.1.0.0(3,5)]octa­ne
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998570/
https://www.ncbi.nlm.nih.gov/pubmed/24826130
http://dx.doi.org/10.1107/S1600536814004826
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