1,5-Bis(2-hy­droxy-3-meth­oxy­benzyl­idene)carbonohydrazide methanol 0.47-solvate

In the title compound, C(17)H(18)N(4)O(5)·0.47CH(3)OH, the virtually planar (r.m.s. deviation = 0.128 Å) carbonohydrazide mol­ecule is located on a twofold axis and conformation of its C=N bonds is E. There are short intra­molecular O—H⋯N hydrogen bonds between the hy­droxy groups and hydrazide N at...

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Autores principales: Sow, Mouhamadou Moustapha, Diouf, Ousmane, Seck, Matar, Barry, Aliou Hamady, Gaye, Mohamed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998575/
https://www.ncbi.nlm.nih.gov/pubmed/24826134
http://dx.doi.org/10.1107/S1600536814004802
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author Sow, Mouhamadou Moustapha
Diouf, Ousmane
Seck, Matar
Barry, Aliou Hamady
Gaye, Mohamed
author_facet Sow, Mouhamadou Moustapha
Diouf, Ousmane
Seck, Matar
Barry, Aliou Hamady
Gaye, Mohamed
author_sort Sow, Mouhamadou Moustapha
collection PubMed
description In the title compound, C(17)H(18)N(4)O(5)·0.47CH(3)OH, the virtually planar (r.m.s. deviation = 0.128 Å) carbonohydrazide mol­ecule is located on a twofold axis and conformation of its C=N bonds is E. There are short intra­molecular O—H⋯N hydrogen bonds between the hy­droxy groups and hydrazide N atoms. In the crystal, bifurcated N—H⋯(O,O) hydrogen bonds assemble the carbonohydrazide mol­ecules into a three-dimensional network. There are C (2) symmetric voids in this network, 47% of which are occupied by disordered methanol mol­ecules.
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spelling pubmed-39985752014-05-13 1,5-Bis(2-hy­droxy-3-meth­oxy­benzyl­idene)carbonohydrazide methanol 0.47-solvate Sow, Mouhamadou Moustapha Diouf, Ousmane Seck, Matar Barry, Aliou Hamady Gaye, Mohamed Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(18)N(4)O(5)·0.47CH(3)OH, the virtually planar (r.m.s. deviation = 0.128 Å) carbonohydrazide mol­ecule is located on a twofold axis and conformation of its C=N bonds is E. There are short intra­molecular O—H⋯N hydrogen bonds between the hy­droxy groups and hydrazide N atoms. In the crystal, bifurcated N—H⋯(O,O) hydrogen bonds assemble the carbonohydrazide mol­ecules into a three-dimensional network. There are C (2) symmetric voids in this network, 47% of which are occupied by disordered methanol mol­ecules. International Union of Crystallography 2014-03-12 /pmc/articles/PMC3998575/ /pubmed/24826134 http://dx.doi.org/10.1107/S1600536814004802 Text en © Sow et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sow, Mouhamadou Moustapha
Diouf, Ousmane
Seck, Matar
Barry, Aliou Hamady
Gaye, Mohamed
1,5-Bis(2-hy­droxy-3-meth­oxy­benzyl­idene)carbonohydrazide methanol 0.47-solvate
title 1,5-Bis(2-hy­droxy-3-meth­oxy­benzyl­idene)carbonohydrazide methanol 0.47-solvate
title_full 1,5-Bis(2-hy­droxy-3-meth­oxy­benzyl­idene)carbonohydrazide methanol 0.47-solvate
title_fullStr 1,5-Bis(2-hy­droxy-3-meth­oxy­benzyl­idene)carbonohydrazide methanol 0.47-solvate
title_full_unstemmed 1,5-Bis(2-hy­droxy-3-meth­oxy­benzyl­idene)carbonohydrazide methanol 0.47-solvate
title_short 1,5-Bis(2-hy­droxy-3-meth­oxy­benzyl­idene)carbonohydrazide methanol 0.47-solvate
title_sort 1,5-bis(2-hy­droxy-3-meth­oxy­benzyl­idene)carbonohydrazide methanol 0.47-solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998575/
https://www.ncbi.nlm.nih.gov/pubmed/24826134
http://dx.doi.org/10.1107/S1600536814004802
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