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{2,6-Bis[(pyridin-2-yl)sulfanylmethyl]pyridine-κ(2) N,N′}(η(3)-prop-2-enyl)palladium(II) hexafluorophosphate
The title compound, [Pd(C(3)H(5))(C(17)H(15)N(3)S(2))]PF(6), is built up by a [(η(3)-allyl)Pd](2+) fragment coordinated by a 2,6-bis[(pyridin-2-yl)sulfanylmethyl]pyridine ligand coordinated through the N atoms. One of the S atoms is at a close distance to the metal centeratom [3.2930 (8) Å]. The...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998576/ https://www.ncbi.nlm.nih.gov/pubmed/24826097 http://dx.doi.org/10.1107/S1600536814003961 |
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author | Bruno, Giuseppe Nicolò, Francesco Tresoldi, Giuseppe Drommi, Dario Mollica Nardo, Viviana |
author_facet | Bruno, Giuseppe Nicolò, Francesco Tresoldi, Giuseppe Drommi, Dario Mollica Nardo, Viviana |
author_sort | Bruno, Giuseppe |
collection | PubMed |
description | The title compound, [Pd(C(3)H(5))(C(17)H(15)N(3)S(2))]PF(6), is built up by a [(η(3)-allyl)Pd](2+) fragment coordinated by a 2,6-bis[(pyridin-2-yl)sulfanylmethyl]pyridine ligand coordinated through the N atoms. One of the S atoms is at a close distance to the metal centeratom [3.2930 (8) Å]. The Pd(II) atom is tetracoordinated in a strongly distorted square-planar environment mainly determined by the η(3)-allyl anion in which the central C atom is disordered over two equally occupied positions. The crystal packing is very compact and is characterized by a three-dimensional network of C—H⋯F interactions between the F atoms of each anion and several H atoms of the surrounding cationic complexes. |
format | Online Article Text |
id | pubmed-3998576 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39985762014-05-13 {2,6-Bis[(pyridin-2-yl)sulfanylmethyl]pyridine-κ(2) N,N′}(η(3)-prop-2-enyl)palladium(II) hexafluorophosphate Bruno, Giuseppe Nicolò, Francesco Tresoldi, Giuseppe Drommi, Dario Mollica Nardo, Viviana Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pd(C(3)H(5))(C(17)H(15)N(3)S(2))]PF(6), is built up by a [(η(3)-allyl)Pd](2+) fragment coordinated by a 2,6-bis[(pyridin-2-yl)sulfanylmethyl]pyridine ligand coordinated through the N atoms. One of the S atoms is at a close distance to the metal centeratom [3.2930 (8) Å]. The Pd(II) atom is tetracoordinated in a strongly distorted square-planar environment mainly determined by the η(3)-allyl anion in which the central C atom is disordered over two equally occupied positions. The crystal packing is very compact and is characterized by a three-dimensional network of C—H⋯F interactions between the F atoms of each anion and several H atoms of the surrounding cationic complexes. International Union of Crystallography 2014-03-15 /pmc/articles/PMC3998576/ /pubmed/24826097 http://dx.doi.org/10.1107/S1600536814003961 Text en © Bruno et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bruno, Giuseppe Nicolò, Francesco Tresoldi, Giuseppe Drommi, Dario Mollica Nardo, Viviana {2,6-Bis[(pyridin-2-yl)sulfanylmethyl]pyridine-κ(2) N,N′}(η(3)-prop-2-enyl)palladium(II) hexafluorophosphate |
title | {2,6-Bis[(pyridin-2-yl)sulfanylmethyl]pyridine-κ(2)
N,N′}(η(3)-prop-2-enyl)palladium(II) hexafluorophosphate |
title_full | {2,6-Bis[(pyridin-2-yl)sulfanylmethyl]pyridine-κ(2)
N,N′}(η(3)-prop-2-enyl)palladium(II) hexafluorophosphate |
title_fullStr | {2,6-Bis[(pyridin-2-yl)sulfanylmethyl]pyridine-κ(2)
N,N′}(η(3)-prop-2-enyl)palladium(II) hexafluorophosphate |
title_full_unstemmed | {2,6-Bis[(pyridin-2-yl)sulfanylmethyl]pyridine-κ(2)
N,N′}(η(3)-prop-2-enyl)palladium(II) hexafluorophosphate |
title_short | {2,6-Bis[(pyridin-2-yl)sulfanylmethyl]pyridine-κ(2)
N,N′}(η(3)-prop-2-enyl)palladium(II) hexafluorophosphate |
title_sort | {2,6-bis[(pyridin-2-yl)sulfanylmethyl]pyridine-κ(2)
n,n′}(η(3)-prop-2-enyl)palladium(ii) hexafluorophosphate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998576/ https://www.ncbi.nlm.nih.gov/pubmed/24826097 http://dx.doi.org/10.1107/S1600536814003961 |
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