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{2,6-Bis[(pyridin-2-yl)sulfanylmeth­yl]pyridine-κ(2) N,N′}(η(3)-prop-2-en­yl)palladium(II) hexa­fluoro­phosphate

The title compound, [Pd(C(3)H(5))(C(17)H(15)N(3)S(2))]PF(6), is built up by a [(η(3)-all­yl)Pd](2+) fragment coordinated by a 2,6-bis­[(pyridin-2-yl)sulfanylmeth­yl]pyridine ligand coordinated through the N atoms. One of the S atoms is at a close distance to the metal centeratom [3.2930 (8) Å]. The...

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Autores principales: Bruno, Giuseppe, Nicolò, Francesco, Tresoldi, Giuseppe, Drommi, Dario, Mollica Nardo, Viviana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998576/
https://www.ncbi.nlm.nih.gov/pubmed/24826097
http://dx.doi.org/10.1107/S1600536814003961
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author Bruno, Giuseppe
Nicolò, Francesco
Tresoldi, Giuseppe
Drommi, Dario
Mollica Nardo, Viviana
author_facet Bruno, Giuseppe
Nicolò, Francesco
Tresoldi, Giuseppe
Drommi, Dario
Mollica Nardo, Viviana
author_sort Bruno, Giuseppe
collection PubMed
description The title compound, [Pd(C(3)H(5))(C(17)H(15)N(3)S(2))]PF(6), is built up by a [(η(3)-all­yl)Pd](2+) fragment coordinated by a 2,6-bis­[(pyridin-2-yl)sulfanylmeth­yl]pyridine ligand coordinated through the N atoms. One of the S atoms is at a close distance to the metal centeratom [3.2930 (8) Å]. The Pd(II) atom is tetra­coordinated in a strongly distorted square-planar environment mainly determined by the η(3)-allyl anion in which the central C atom is disordered over two equally occupied positions. The crystal packing is very compact and is characterized by a three-dimensional network of C—H⋯F interactions between the F atoms of each anion and several H atoms of the surrounding cationic complexes.
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spelling pubmed-39985762014-05-13 {2,6-Bis[(pyridin-2-yl)sulfanylmeth­yl]pyridine-κ(2) N,N′}(η(3)-prop-2-en­yl)palladium(II) hexa­fluoro­phosphate Bruno, Giuseppe Nicolò, Francesco Tresoldi, Giuseppe Drommi, Dario Mollica Nardo, Viviana Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pd(C(3)H(5))(C(17)H(15)N(3)S(2))]PF(6), is built up by a [(η(3)-all­yl)Pd](2+) fragment coordinated by a 2,6-bis­[(pyridin-2-yl)sulfanylmeth­yl]pyridine ligand coordinated through the N atoms. One of the S atoms is at a close distance to the metal centeratom [3.2930 (8) Å]. The Pd(II) atom is tetra­coordinated in a strongly distorted square-planar environment mainly determined by the η(3)-allyl anion in which the central C atom is disordered over two equally occupied positions. The crystal packing is very compact and is characterized by a three-dimensional network of C—H⋯F interactions between the F atoms of each anion and several H atoms of the surrounding cationic complexes. International Union of Crystallography 2014-03-15 /pmc/articles/PMC3998576/ /pubmed/24826097 http://dx.doi.org/10.1107/S1600536814003961 Text en © Bruno et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bruno, Giuseppe
Nicolò, Francesco
Tresoldi, Giuseppe
Drommi, Dario
Mollica Nardo, Viviana
{2,6-Bis[(pyridin-2-yl)sulfanylmeth­yl]pyridine-κ(2) N,N′}(η(3)-prop-2-en­yl)palladium(II) hexa­fluoro­phosphate
title {2,6-Bis[(pyridin-2-yl)sulfanylmeth­yl]pyridine-κ(2) N,N′}(η(3)-prop-2-en­yl)palladium(II) hexa­fluoro­phosphate
title_full {2,6-Bis[(pyridin-2-yl)sulfanylmeth­yl]pyridine-κ(2) N,N′}(η(3)-prop-2-en­yl)palladium(II) hexa­fluoro­phosphate
title_fullStr {2,6-Bis[(pyridin-2-yl)sulfanylmeth­yl]pyridine-κ(2) N,N′}(η(3)-prop-2-en­yl)palladium(II) hexa­fluoro­phosphate
title_full_unstemmed {2,6-Bis[(pyridin-2-yl)sulfanylmeth­yl]pyridine-κ(2) N,N′}(η(3)-prop-2-en­yl)palladium(II) hexa­fluoro­phosphate
title_short {2,6-Bis[(pyridin-2-yl)sulfanylmeth­yl]pyridine-κ(2) N,N′}(η(3)-prop-2-en­yl)palladium(II) hexa­fluoro­phosphate
title_sort {2,6-bis[(pyridin-2-yl)sulfanylmeth­yl]pyridine-κ(2) n,n′}(η(3)-prop-2-en­yl)palladium(ii) hexa­fluoro­phosphate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998576/
https://www.ncbi.nlm.nih.gov/pubmed/24826097
http://dx.doi.org/10.1107/S1600536814003961
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