5-Bromo-2,4,6-trimethyl-3-(3-methyl­phenyl­sulfin­yl)-1-benzo­furan

In the title compound, C(18)H(17)BrO(2)S, the dihedral angle between the mean plane of the benzo­furan ring system and the benzene ring is 68.58 (4)°. In the crystal, mol­ecules are linked via pairs of C—H⋯O hydrogen bonds into inversion dimers. These dimers are linked by C—H⋯O hydrogen bonds and π–...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Lee, Uk
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998578/
https://www.ncbi.nlm.nih.gov/pubmed/24826141
http://dx.doi.org/10.1107/S1600536814005352
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author Choi, Hong Dae
Seo, Pil Ja
Lee, Uk
author_facet Choi, Hong Dae
Seo, Pil Ja
Lee, Uk
author_sort Choi, Hong Dae
collection PubMed
description In the title compound, C(18)H(17)BrO(2)S, the dihedral angle between the mean plane of the benzo­furan ring system and the benzene ring is 68.58 (4)°. In the crystal, mol­ecules are linked via pairs of C—H⋯O hydrogen bonds into inversion dimers. These dimers are linked by C—H⋯O hydrogen bonds and π–π inter­actions between the benzene rings of neighbouring mol­ecules [centroid–centroid distance = 3.783 (1) Å], forming a three-dimensional network. In addition, the stacked mol­ecules exhibit inversion-related S⋯O contacts [3.153 (1) Å] involving the sulfinyl groups.
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spelling pubmed-39985782014-05-13 5-Bromo-2,4,6-trimethyl-3-(3-methyl­phenyl­sulfin­yl)-1-benzo­furan Choi, Hong Dae Seo, Pil Ja Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(17)BrO(2)S, the dihedral angle between the mean plane of the benzo­furan ring system and the benzene ring is 68.58 (4)°. In the crystal, mol­ecules are linked via pairs of C—H⋯O hydrogen bonds into inversion dimers. These dimers are linked by C—H⋯O hydrogen bonds and π–π inter­actions between the benzene rings of neighbouring mol­ecules [centroid–centroid distance = 3.783 (1) Å], forming a three-dimensional network. In addition, the stacked mol­ecules exhibit inversion-related S⋯O contacts [3.153 (1) Å] involving the sulfinyl groups. International Union of Crystallography 2014-03-15 /pmc/articles/PMC3998578/ /pubmed/24826141 http://dx.doi.org/10.1107/S1600536814005352 Text en © Choi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Choi, Hong Dae
Seo, Pil Ja
Lee, Uk
5-Bromo-2,4,6-trimethyl-3-(3-methyl­phenyl­sulfin­yl)-1-benzo­furan
title 5-Bromo-2,4,6-trimethyl-3-(3-methyl­phenyl­sulfin­yl)-1-benzo­furan
title_full 5-Bromo-2,4,6-trimethyl-3-(3-methyl­phenyl­sulfin­yl)-1-benzo­furan
title_fullStr 5-Bromo-2,4,6-trimethyl-3-(3-methyl­phenyl­sulfin­yl)-1-benzo­furan
title_full_unstemmed 5-Bromo-2,4,6-trimethyl-3-(3-methyl­phenyl­sulfin­yl)-1-benzo­furan
title_short 5-Bromo-2,4,6-trimethyl-3-(3-methyl­phenyl­sulfin­yl)-1-benzo­furan
title_sort 5-bromo-2,4,6-trimethyl-3-(3-methyl­phenyl­sulfin­yl)-1-benzo­furan
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998578/
https://www.ncbi.nlm.nih.gov/pubmed/24826141
http://dx.doi.org/10.1107/S1600536814005352
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