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(But­oxy­methyl­idene)di­methyl­aza­nium tetra­phenyl­borate aceto­nitrile monosolvate

In the title solvated salt, C(7)H(16)NO(+)·C(24)H(20)B(−)·C(2)H(3)N, the C—N bond lengths in the cation are 1.2831 (19), 1.467 (2) and 1.465 (2) Å, indicating double- and single-bond character, respectively. The C—O bond length of 1.2950 (18) Å shows a double-bond character, pointing towards charge...

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Detalles Bibliográficos
Autores principales: Tiritiris, Ioannis, Saur, Stefan, Kantlehner, Willi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998583/
https://www.ncbi.nlm.nih.gov/pubmed/24826158
http://dx.doi.org/10.1107/S1600536814005674
Descripción
Sumario:In the title solvated salt, C(7)H(16)NO(+)·C(24)H(20)B(−)·C(2)H(3)N, the C—N bond lengths in the cation are 1.2831 (19), 1.467 (2) and 1.465 (2) Å, indicating double- and single-bond character, respectively. The C—O bond length of 1.2950 (18) Å shows a double-bond character, pointing towards charge delocalization within the NCO plane of the iminium ion. The two C atoms of the n-butyl group are disordered over the two sites, with refined occupancy ratios of 0.890 (5):0.110 (5) and 0.888 (4):0.112 (4). In the crystal, C—H⋯π inter­actions occur between the methine H atom, H atoms of the –N(CH(3))(2) and –CH(2) groups of the cation, and two of the phenyl rings of the tetra­phenyl­borate anion. The latter inter­action forms an aromatic pocket in which the cation is embedded. Thus, a two-dimensional pattern is created in the ac plane.