Cargando…
(Butoxymethylidene)dimethylazanium tetraphenylborate acetonitrile monosolvate
In the title solvated salt, C(7)H(16)NO(+)·C(24)H(20)B(−)·C(2)H(3)N, the C—N bond lengths in the cation are 1.2831 (19), 1.467 (2) and 1.465 (2) Å, indicating double- and single-bond character, respectively. The C—O bond length of 1.2950 (18) Å shows a double-bond character, pointing towards charge...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998583/ https://www.ncbi.nlm.nih.gov/pubmed/24826158 http://dx.doi.org/10.1107/S1600536814005674 |
Sumario: | In the title solvated salt, C(7)H(16)NO(+)·C(24)H(20)B(−)·C(2)H(3)N, the C—N bond lengths in the cation are 1.2831 (19), 1.467 (2) and 1.465 (2) Å, indicating double- and single-bond character, respectively. The C—O bond length of 1.2950 (18) Å shows a double-bond character, pointing towards charge delocalization within the NCO plane of the iminium ion. The two C atoms of the n-butyl group are disordered over the two sites, with refined occupancy ratios of 0.890 (5):0.110 (5) and 0.888 (4):0.112 (4). In the crystal, C—H⋯π interactions occur between the methine H atom, H atoms of the –N(CH(3))(2) and –CH(2) groups of the cation, and two of the phenyl rings of the tetraphenylborate anion. The latter interaction forms an aromatic pocket in which the cation is embedded. Thus, a two-dimensional pattern is created in the ac plane. |
---|