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Bis(μ-nitrato-κ(2) O:O)bis{[1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane-κ(2) P,P′]silver(I)} dichloromethane disolvate
The title compound, [Ag(2)(NO(3))(2)(C(14)H(38)B(10)P(2))(2)]·2CH(2)Cl(2), was synthesized by the reaction of 1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane with AgNO(3). The resulting dinuclear molecule has crystallographically imposed inversion symmetry. The diisopropylphosph...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998584/ https://www.ncbi.nlm.nih.gov/pubmed/24826102 http://dx.doi.org/10.1107/S1600536814006084 |
Sumario: | The title compound, [Ag(2)(NO(3))(2)(C(14)H(38)B(10)P(2))(2)]·2CH(2)Cl(2), was synthesized by the reaction of 1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane with AgNO(3). The resulting dinuclear molecule has crystallographically imposed inversion symmetry. The diisopropylphosphanyl-closo-carborane ligand is coordinated in a bidentate manner to the Ag(I) atom through the two P atoms. The distorted tetrahedral coordination of the metal is completed by two O atoms of two bridging nitrate anions. The separation between the two Ag(I) atoms is 3.8913 (5) Å. C—H⋯O hydrogen bonds are observed involving the dichloromethane solvent molecule and the nitrate anion. |
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