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Bis(μ-nitrato-κ(2) O:O)bis­{[1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′]silver(I)} di­chloro­methane disolvate

The title compound, [Ag(2)(NO(3))(2)(C(14)H(38)B(10)P(2))(2)]·2CH(2)Cl(2), was synthesized by the reaction of 1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane with AgNO(3). The resulting dinuclear molecule has crystallographically imposed inversion symmetry. The diiso­propyl­phosph...

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Detalles Bibliográficos
Autor principal: Yang, Liguo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998584/
https://www.ncbi.nlm.nih.gov/pubmed/24826102
http://dx.doi.org/10.1107/S1600536814006084
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author Yang, Liguo
author_facet Yang, Liguo
author_sort Yang, Liguo
collection PubMed
description The title compound, [Ag(2)(NO(3))(2)(C(14)H(38)B(10)P(2))(2)]·2CH(2)Cl(2), was synthesized by the reaction of 1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane with AgNO(3). The resulting dinuclear molecule has crystallographically imposed inversion symmetry. The diiso­propyl­phosphanyl-closo-carborane ligand is coordin­ated in a bidentate manner to the Ag(I) atom through the two P atoms. The distorted tetra­hedral coordination of the metal is completed by two O atoms of two bridging nitrate anions. The separation between the two Ag(I) atoms is 3.8913 (5) Å. C—H⋯O hydrogen bonds are observed involving the dichloromethane solvent molecule and the nitrate anion.
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spelling pubmed-39985842014-05-13 Bis(μ-nitrato-κ(2) O:O)bis­{[1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′]silver(I)} di­chloro­methane disolvate Yang, Liguo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ag(2)(NO(3))(2)(C(14)H(38)B(10)P(2))(2)]·2CH(2)Cl(2), was synthesized by the reaction of 1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane with AgNO(3). The resulting dinuclear molecule has crystallographically imposed inversion symmetry. The diiso­propyl­phosphanyl-closo-carborane ligand is coordin­ated in a bidentate manner to the Ag(I) atom through the two P atoms. The distorted tetra­hedral coordination of the metal is completed by two O atoms of two bridging nitrate anions. The separation between the two Ag(I) atoms is 3.8913 (5) Å. C—H⋯O hydrogen bonds are observed involving the dichloromethane solvent molecule and the nitrate anion. International Union of Crystallography 2014-03-22 /pmc/articles/PMC3998584/ /pubmed/24826102 http://dx.doi.org/10.1107/S1600536814006084 Text en © Liguo Yang 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Liguo
Bis(μ-nitrato-κ(2) O:O)bis­{[1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′]silver(I)} di­chloro­methane disolvate
title Bis(μ-nitrato-κ(2) O:O)bis­{[1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′]silver(I)} di­chloro­methane disolvate
title_full Bis(μ-nitrato-κ(2) O:O)bis­{[1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′]silver(I)} di­chloro­methane disolvate
title_fullStr Bis(μ-nitrato-κ(2) O:O)bis­{[1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′]silver(I)} di­chloro­methane disolvate
title_full_unstemmed Bis(μ-nitrato-κ(2) O:O)bis­{[1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′]silver(I)} di­chloro­methane disolvate
title_short Bis(μ-nitrato-κ(2) O:O)bis­{[1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′]silver(I)} di­chloro­methane disolvate
title_sort bis(μ-nitrato-κ(2) o:o)bis­{[1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane-κ(2) p,p′]silver(i)} di­chloro­methane disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998584/
https://www.ncbi.nlm.nih.gov/pubmed/24826102
http://dx.doi.org/10.1107/S1600536814006084
work_keys_str_mv AT yangliguo bismnitratok2oobis12bisdiisopropylphosphanyl12dicarbaclosododecaboranek2ppsilveridichloromethanedisolvate