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Bis(μ-nitrato-κ(2) O:O)bis{[1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane-κ(2) P,P′]silver(I)} dichloromethane disolvate
The title compound, [Ag(2)(NO(3))(2)(C(14)H(38)B(10)P(2))(2)]·2CH(2)Cl(2), was synthesized by the reaction of 1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane with AgNO(3). The resulting dinuclear molecule has crystallographically imposed inversion symmetry. The diisopropylphosph...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998584/ https://www.ncbi.nlm.nih.gov/pubmed/24826102 http://dx.doi.org/10.1107/S1600536814006084 |
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author | Yang, Liguo |
author_facet | Yang, Liguo |
author_sort | Yang, Liguo |
collection | PubMed |
description | The title compound, [Ag(2)(NO(3))(2)(C(14)H(38)B(10)P(2))(2)]·2CH(2)Cl(2), was synthesized by the reaction of 1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane with AgNO(3). The resulting dinuclear molecule has crystallographically imposed inversion symmetry. The diisopropylphosphanyl-closo-carborane ligand is coordinated in a bidentate manner to the Ag(I) atom through the two P atoms. The distorted tetrahedral coordination of the metal is completed by two O atoms of two bridging nitrate anions. The separation between the two Ag(I) atoms is 3.8913 (5) Å. C—H⋯O hydrogen bonds are observed involving the dichloromethane solvent molecule and the nitrate anion. |
format | Online Article Text |
id | pubmed-3998584 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39985842014-05-13 Bis(μ-nitrato-κ(2) O:O)bis{[1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane-κ(2) P,P′]silver(I)} dichloromethane disolvate Yang, Liguo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ag(2)(NO(3))(2)(C(14)H(38)B(10)P(2))(2)]·2CH(2)Cl(2), was synthesized by the reaction of 1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane with AgNO(3). The resulting dinuclear molecule has crystallographically imposed inversion symmetry. The diisopropylphosphanyl-closo-carborane ligand is coordinated in a bidentate manner to the Ag(I) atom through the two P atoms. The distorted tetrahedral coordination of the metal is completed by two O atoms of two bridging nitrate anions. The separation between the two Ag(I) atoms is 3.8913 (5) Å. C—H⋯O hydrogen bonds are observed involving the dichloromethane solvent molecule and the nitrate anion. International Union of Crystallography 2014-03-22 /pmc/articles/PMC3998584/ /pubmed/24826102 http://dx.doi.org/10.1107/S1600536814006084 Text en © Liguo Yang 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yang, Liguo Bis(μ-nitrato-κ(2) O:O)bis{[1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane-κ(2) P,P′]silver(I)} dichloromethane disolvate |
title | Bis(μ-nitrato-κ(2)
O:O)bis{[1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane-κ(2)
P,P′]silver(I)} dichloromethane disolvate |
title_full | Bis(μ-nitrato-κ(2)
O:O)bis{[1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane-κ(2)
P,P′]silver(I)} dichloromethane disolvate |
title_fullStr | Bis(μ-nitrato-κ(2)
O:O)bis{[1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane-κ(2)
P,P′]silver(I)} dichloromethane disolvate |
title_full_unstemmed | Bis(μ-nitrato-κ(2)
O:O)bis{[1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane-κ(2)
P,P′]silver(I)} dichloromethane disolvate |
title_short | Bis(μ-nitrato-κ(2)
O:O)bis{[1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane-κ(2)
P,P′]silver(I)} dichloromethane disolvate |
title_sort | bis(μ-nitrato-κ(2)
o:o)bis{[1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane-κ(2)
p,p′]silver(i)} dichloromethane disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998584/ https://www.ncbi.nlm.nih.gov/pubmed/24826102 http://dx.doi.org/10.1107/S1600536814006084 |
work_keys_str_mv | AT yangliguo bismnitratok2oobis12bisdiisopropylphosphanyl12dicarbaclosododecaboranek2ppsilveridichloromethanedisolvate |