{N,N′-Bis­[2-(di­phenyl­phosphan­yl)ethan-1-yl­idene]ethyl­enedi­amine}bromido­(p-toluene­sulfonyl­methyl isocyanide)iron(II) tetra­phenyl­borate

In the title compound, [FeBr(C(9)H(9)NO(2)S)(C(30)H(30)N(2)P(2))][B(C(6)H(5))(4)], the Fe(II) ion is in a distorted octa­hedral CBrN(2)P(2) coordination geometry with a P—Fe—P angle of 109.95 (3)°. The relative orientation of the p-toluene­sulfonyl­methyl isocyanide ligand is defined by the C—S—C—N...

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Detalles Bibliográficos
Autores principales: Sues, Peter E., Lough, Alan J., Morris, Robert H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998587/
https://www.ncbi.nlm.nih.gov/pubmed/24826104
http://dx.doi.org/10.1107/S1600536814005467
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author Sues, Peter E.
Lough, Alan J.
Morris, Robert H.
author_facet Sues, Peter E.
Lough, Alan J.
Morris, Robert H.
author_sort Sues, Peter E.
collection PubMed
description In the title compound, [FeBr(C(9)H(9)NO(2)S)(C(30)H(30)N(2)P(2))][B(C(6)H(5))(4)], the Fe(II) ion is in a distorted octa­hedral CBrN(2)P(2) coordination geometry with a P—Fe—P angle of 109.95 (3)°. The relative orientation of the p-toluene­sulfonyl­methyl isocyanide ligand is defined by the C—S—C—N torsion angle of 67.1 (2)°. In the crystal, pairs of weak C—H⋯O hydrogen bonds connect the cations into inversion dimers, forming R (2) (2)(8) rings.
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spelling pubmed-39985872014-05-13 {N,N′-Bis­[2-(di­phenyl­phosphan­yl)ethan-1-yl­idene]ethyl­enedi­amine}bromido­(p-toluene­sulfonyl­methyl isocyanide)iron(II) tetra­phenyl­borate Sues, Peter E. Lough, Alan J. Morris, Robert H. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [FeBr(C(9)H(9)NO(2)S)(C(30)H(30)N(2)P(2))][B(C(6)H(5))(4)], the Fe(II) ion is in a distorted octa­hedral CBrN(2)P(2) coordination geometry with a P—Fe—P angle of 109.95 (3)°. The relative orientation of the p-toluene­sulfonyl­methyl isocyanide ligand is defined by the C—S—C—N torsion angle of 67.1 (2)°. In the crystal, pairs of weak C—H⋯O hydrogen bonds connect the cations into inversion dimers, forming R (2) (2)(8) rings. International Union of Crystallography 2014-03-26 /pmc/articles/PMC3998587/ /pubmed/24826104 http://dx.doi.org/10.1107/S1600536814005467 Text en © Sues et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sues, Peter E.
Lough, Alan J.
Morris, Robert H.
{N,N′-Bis­[2-(di­phenyl­phosphan­yl)ethan-1-yl­idene]ethyl­enedi­amine}bromido­(p-toluene­sulfonyl­methyl isocyanide)iron(II) tetra­phenyl­borate
title {N,N′-Bis­[2-(di­phenyl­phosphan­yl)ethan-1-yl­idene]ethyl­enedi­amine}bromido­(p-toluene­sulfonyl­methyl isocyanide)iron(II) tetra­phenyl­borate
title_full {N,N′-Bis­[2-(di­phenyl­phosphan­yl)ethan-1-yl­idene]ethyl­enedi­amine}bromido­(p-toluene­sulfonyl­methyl isocyanide)iron(II) tetra­phenyl­borate
title_fullStr {N,N′-Bis­[2-(di­phenyl­phosphan­yl)ethan-1-yl­idene]ethyl­enedi­amine}bromido­(p-toluene­sulfonyl­methyl isocyanide)iron(II) tetra­phenyl­borate
title_full_unstemmed {N,N′-Bis­[2-(di­phenyl­phosphan­yl)ethan-1-yl­idene]ethyl­enedi­amine}bromido­(p-toluene­sulfonyl­methyl isocyanide)iron(II) tetra­phenyl­borate
title_short {N,N′-Bis­[2-(di­phenyl­phosphan­yl)ethan-1-yl­idene]ethyl­enedi­amine}bromido­(p-toluene­sulfonyl­methyl isocyanide)iron(II) tetra­phenyl­borate
title_sort {n,n′-bis­[2-(di­phenyl­phosphan­yl)ethan-1-yl­idene]ethyl­enedi­amine}bromido­(p-toluene­sulfonyl­methyl isocyanide)iron(ii) tetra­phenyl­borate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998587/
https://www.ncbi.nlm.nih.gov/pubmed/24826104
http://dx.doi.org/10.1107/S1600536814005467
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AT morrisroberth nnbis2diphenylphosphanylethan1ylideneethylenediaminebromidoptoluenesulfonylmethylisocyanideironiitetraphenylborate

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