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{2-[(1H-Indol-3-yl­methyl­idene)amino]-4,5,6,7-tetra­hydro­benzo[b]thio­phen-3-yl}(phen­yl)methanone

The title compound, C(24)H(20)N(2)OS, crystallizes with two independent mol­ecules (A and B) in the asymmetric unit, in each of which the cyclo­hexene rings adopt half-chair conformations. The mean plane of the indole ring is twisted from those of the phenyl and thio­phene rings by 69.0 (7) and 8.3 ...

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Detalles Bibliográficos
Autores principales: Kaur, Manpreet, Jasinski, Jerry P., Yamuna, Thammarse S., Yathirajan, H. S., Byrappa, K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998588/
https://www.ncbi.nlm.nih.gov/pubmed/24826189
http://dx.doi.org/10.1107/S1600536814006345
Descripción
Sumario:The title compound, C(24)H(20)N(2)OS, crystallizes with two independent mol­ecules (A and B) in the asymmetric unit, in each of which the cyclo­hexene rings adopt half-chair conformations. The mean plane of the indole ring is twisted from those of the phenyl and thio­phene rings by 69.0 (7) and 8.3 (5)°, respectively, in mol­ecule A and by 65.4 (9) and 6.7 (5)°, respectively, in mol­ecule B. The dihedral angles between the mean planes of the phenyl and thio­phene rings are 63.0 (4) and 58.8 (9)° in mol­ecules A and B, respectively. In the crystal, N—H⋯O hydrogen bonds lead to the formation of an infinite chain along [101]. In addition, π–π stacking inter­actions are observed involving the thio­phene and pyrrole rings of the two mol­ecules, with a shortest inter­centroid distance of 3.468 (2) Å.