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Dimethylammonium tetraaqua(hydrogensulfato)sulfatocuprate(II)
In the title salt, [(CH(3))(2)NH(2)][Cu(HSO(4))(SO(4))(H(2)O)(4)], one type of cation and anion is present in the asymmetric unit. The Cu(II) atom in the complex anion, [Cu(HSO(4))(SO(4))(H(2)O)(4)](−), has a tetragonal bipyramidal [4 + 2] coordination caused by a Jahn–Teller distortion, with the a...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998589/ https://www.ncbi.nlm.nih.gov/pubmed/24826087 http://dx.doi.org/10.1107/S1600536814004486 |
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author | Held, Peter |
author_facet | Held, Peter |
author_sort | Held, Peter |
collection | PubMed |
description | In the title salt, [(CH(3))(2)NH(2)][Cu(HSO(4))(SO(4))(H(2)O)(4)], one type of cation and anion is present in the asymmetric unit. The Cu(II) atom in the complex anion, [Cu(HSO(4))(SO(4))(H(2)O)(4)](−), has a tetragonal bipyramidal [4 + 2] coordination caused by a Jahn–Teller distortion, with the aqua ligands in equatorial and two O atoms of tetrahedral HSO(4) and SO(4) units in apical positions. Both types of ions form sheets parallel to (010). The interconnection within and between the sheets is reinforced by O—H⋯O and N—H⋯O hydrogen bonds, respectively, involving the water molecules, the two types of sulfate anions and the ammonium groups. |
format | Online Article Text |
id | pubmed-3998589 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39985892014-05-13 Dimethylammonium tetraaqua(hydrogensulfato)sulfatocuprate(II) Held, Peter Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [(CH(3))(2)NH(2)][Cu(HSO(4))(SO(4))(H(2)O)(4)], one type of cation and anion is present in the asymmetric unit. The Cu(II) atom in the complex anion, [Cu(HSO(4))(SO(4))(H(2)O)(4)](−), has a tetragonal bipyramidal [4 + 2] coordination caused by a Jahn–Teller distortion, with the aqua ligands in equatorial and two O atoms of tetrahedral HSO(4) and SO(4) units in apical positions. Both types of ions form sheets parallel to (010). The interconnection within and between the sheets is reinforced by O—H⋯O and N—H⋯O hydrogen bonds, respectively, involving the water molecules, the two types of sulfate anions and the ammonium groups. International Union of Crystallography 2014-03-05 /pmc/articles/PMC3998589/ /pubmed/24826087 http://dx.doi.org/10.1107/S1600536814004486 Text en © Peter Held 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Held, Peter Dimethylammonium tetraaqua(hydrogensulfato)sulfatocuprate(II) |
title | Dimethylammonium tetraaqua(hydrogensulfato)sulfatocuprate(II) |
title_full | Dimethylammonium tetraaqua(hydrogensulfato)sulfatocuprate(II) |
title_fullStr | Dimethylammonium tetraaqua(hydrogensulfato)sulfatocuprate(II) |
title_full_unstemmed | Dimethylammonium tetraaqua(hydrogensulfato)sulfatocuprate(II) |
title_short | Dimethylammonium tetraaqua(hydrogensulfato)sulfatocuprate(II) |
title_sort | dimethylammonium tetraaqua(hydrogensulfato)sulfatocuprate(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998589/ https://www.ncbi.nlm.nih.gov/pubmed/24826087 http://dx.doi.org/10.1107/S1600536814004486 |
work_keys_str_mv | AT heldpeter dimethylammoniumtetraaquahydrogensulfatosulfatocuprateii |