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Di­methyl­ammonium tetra­aqua­(hydrogen­sulfato)­sulfato­cuprate(II)

In the title salt, [(CH(3))(2)NH(2)][Cu(HSO(4))(SO(4))(H(2)O)(4)], one type of cation and anion is present in the asymmetric unit. The Cu(II) atom in the complex anion, [Cu(HSO(4))(SO(4))(H(2)O)(4)](−), has a tetra­gonal bipyramidal [4 + 2] coordination caused by a Jahn–Teller distortion, with the a...

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Autor principal: Held, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998589/
https://www.ncbi.nlm.nih.gov/pubmed/24826087
http://dx.doi.org/10.1107/S1600536814004486
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author Held, Peter
author_facet Held, Peter
author_sort Held, Peter
collection PubMed
description In the title salt, [(CH(3))(2)NH(2)][Cu(HSO(4))(SO(4))(H(2)O)(4)], one type of cation and anion is present in the asymmetric unit. The Cu(II) atom in the complex anion, [Cu(HSO(4))(SO(4))(H(2)O)(4)](−), has a tetra­gonal bipyramidal [4 + 2] coordination caused by a Jahn–Teller distortion, with the aqua ligands in equatorial and two O atoms of tetra­hedral HSO(4) and SO(4) units in apical positions. Both types of ions form sheets parallel to (010). The inter­connection within and between the sheets is reinforced by O—H⋯O and N—H⋯O hydrogen bonds, respectively, involving the water mol­ecules, the two types of sulfate anions and the ammonium groups.
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spelling pubmed-39985892014-05-13 Di­methyl­ammonium tetra­aqua­(hydrogen­sulfato)­sulfato­cuprate(II) Held, Peter Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [(CH(3))(2)NH(2)][Cu(HSO(4))(SO(4))(H(2)O)(4)], one type of cation and anion is present in the asymmetric unit. The Cu(II) atom in the complex anion, [Cu(HSO(4))(SO(4))(H(2)O)(4)](−), has a tetra­gonal bipyramidal [4 + 2] coordination caused by a Jahn–Teller distortion, with the aqua ligands in equatorial and two O atoms of tetra­hedral HSO(4) and SO(4) units in apical positions. Both types of ions form sheets parallel to (010). The inter­connection within and between the sheets is reinforced by O—H⋯O and N—H⋯O hydrogen bonds, respectively, involving the water mol­ecules, the two types of sulfate anions and the ammonium groups. International Union of Crystallography 2014-03-05 /pmc/articles/PMC3998589/ /pubmed/24826087 http://dx.doi.org/10.1107/S1600536814004486 Text en © Peter Held 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Held, Peter
Di­methyl­ammonium tetra­aqua­(hydrogen­sulfato)­sulfato­cuprate(II)
title Di­methyl­ammonium tetra­aqua­(hydrogen­sulfato)­sulfato­cuprate(II)
title_full Di­methyl­ammonium tetra­aqua­(hydrogen­sulfato)­sulfato­cuprate(II)
title_fullStr Di­methyl­ammonium tetra­aqua­(hydrogen­sulfato)­sulfato­cuprate(II)
title_full_unstemmed Di­methyl­ammonium tetra­aqua­(hydrogen­sulfato)­sulfato­cuprate(II)
title_short Di­methyl­ammonium tetra­aqua­(hydrogen­sulfato)­sulfato­cuprate(II)
title_sort di­methyl­ammonium tetra­aqua­(hydrogen­sulfato)­sulfato­cuprate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998589/
https://www.ncbi.nlm.nih.gov/pubmed/24826087
http://dx.doi.org/10.1107/S1600536814004486
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