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Bis[4-amino-N-(4-methyl­pyrimidin-2-yl-κN (3))benzene­sulfonamidato-κN](2,2′-bi­pyridine-κ(2) N,N′)mercury(II)

The complete mol­ecule of the title complex, [Hg(C(11)H(11)N(4)O(2)S)(2)(C(10)H(8)N(2))], is generated by crystallographic twofold symmetry, with the mercury cation lying on the rotation axis. The mercury coordination polyhedron can be described as tetra­hedral (from the N,N′-bidenate bi­pyridine mo...

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Autores principales: Hossain, G. M. Golzar, Amoroso, A. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998590/
https://www.ncbi.nlm.nih.gov/pubmed/24826092
http://dx.doi.org/10.1107/S1600536814004760
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author Hossain, G. M. Golzar
Amoroso, A. J.
author_facet Hossain, G. M. Golzar
Amoroso, A. J.
author_sort Hossain, G. M. Golzar
collection PubMed
description The complete mol­ecule of the title complex, [Hg(C(11)H(11)N(4)O(2)S)(2)(C(10)H(8)N(2))], is generated by crystallographic twofold symmetry, with the mercury cation lying on the rotation axis. The mercury coordination polyhedron can be described as tetra­hedral (from the N,N′-bidenate bi­pyridine mol­ecule and the sulfonamide N atoms of the sulfamerazine anions) or as squashed trigonal-prismatic, if two long (> 2.80 Å) Hg—N bonds to pyrimidine N atoms are included. The dihedral angle between the aromatic rings in the anion is 73.3 (2)°. In the crystal, N—H⋯(N,O) and N—H⋯N hydrogen bonds link the mol­ecules into a three-dimensional network.
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spelling pubmed-39985902014-05-13 Bis[4-amino-N-(4-methyl­pyrimidin-2-yl-κN (3))benzene­sulfonamidato-κN](2,2′-bi­pyridine-κ(2) N,N′)mercury(II) Hossain, G. M. Golzar Amoroso, A. J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete mol­ecule of the title complex, [Hg(C(11)H(11)N(4)O(2)S)(2)(C(10)H(8)N(2))], is generated by crystallographic twofold symmetry, with the mercury cation lying on the rotation axis. The mercury coordination polyhedron can be described as tetra­hedral (from the N,N′-bidenate bi­pyridine mol­ecule and the sulfonamide N atoms of the sulfamerazine anions) or as squashed trigonal-prismatic, if two long (> 2.80 Å) Hg—N bonds to pyrimidine N atoms are included. The dihedral angle between the aromatic rings in the anion is 73.3 (2)°. In the crystal, N—H⋯(N,O) and N—H⋯N hydrogen bonds link the mol­ecules into a three-dimensional network. International Union of Crystallography 2014-03-08 /pmc/articles/PMC3998590/ /pubmed/24826092 http://dx.doi.org/10.1107/S1600536814004760 Text en © Hossain and Amoroso 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hossain, G. M. Golzar
Amoroso, A. J.
Bis[4-amino-N-(4-methyl­pyrimidin-2-yl-κN (3))benzene­sulfonamidato-κN](2,2′-bi­pyridine-κ(2) N,N′)mercury(II)
title Bis[4-amino-N-(4-methyl­pyrimidin-2-yl-κN (3))benzene­sulfonamidato-κN](2,2′-bi­pyridine-κ(2) N,N′)mercury(II)
title_full Bis[4-amino-N-(4-methyl­pyrimidin-2-yl-κN (3))benzene­sulfonamidato-κN](2,2′-bi­pyridine-κ(2) N,N′)mercury(II)
title_fullStr Bis[4-amino-N-(4-methyl­pyrimidin-2-yl-κN (3))benzene­sulfonamidato-κN](2,2′-bi­pyridine-κ(2) N,N′)mercury(II)
title_full_unstemmed Bis[4-amino-N-(4-methyl­pyrimidin-2-yl-κN (3))benzene­sulfonamidato-κN](2,2′-bi­pyridine-κ(2) N,N′)mercury(II)
title_short Bis[4-amino-N-(4-methyl­pyrimidin-2-yl-κN (3))benzene­sulfonamidato-κN](2,2′-bi­pyridine-κ(2) N,N′)mercury(II)
title_sort bis[4-amino-n-(4-methyl­pyrimidin-2-yl-κn (3))benzene­sulfonamidato-κn](2,2′-bi­pyridine-κ(2) n,n′)mercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998590/
https://www.ncbi.nlm.nih.gov/pubmed/24826092
http://dx.doi.org/10.1107/S1600536814004760
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