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Bis[4-amino-N-(4-methylpyrimidin-2-yl-κN (3))benzenesulfonamidato-κN](2,2′-bipyridine-κ(2) N,N′)mercury(II)
The complete molecule of the title complex, [Hg(C(11)H(11)N(4)O(2)S)(2)(C(10)H(8)N(2))], is generated by crystallographic twofold symmetry, with the mercury cation lying on the rotation axis. The mercury coordination polyhedron can be described as tetrahedral (from the N,N′-bidenate bipyridine mo...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998590/ https://www.ncbi.nlm.nih.gov/pubmed/24826092 http://dx.doi.org/10.1107/S1600536814004760 |
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author | Hossain, G. M. Golzar Amoroso, A. J. |
author_facet | Hossain, G. M. Golzar Amoroso, A. J. |
author_sort | Hossain, G. M. Golzar |
collection | PubMed |
description | The complete molecule of the title complex, [Hg(C(11)H(11)N(4)O(2)S)(2)(C(10)H(8)N(2))], is generated by crystallographic twofold symmetry, with the mercury cation lying on the rotation axis. The mercury coordination polyhedron can be described as tetrahedral (from the N,N′-bidenate bipyridine molecule and the sulfonamide N atoms of the sulfamerazine anions) or as squashed trigonal-prismatic, if two long (> 2.80 Å) Hg—N bonds to pyrimidine N atoms are included. The dihedral angle between the aromatic rings in the anion is 73.3 (2)°. In the crystal, N—H⋯(N,O) and N—H⋯N hydrogen bonds link the molecules into a three-dimensional network. |
format | Online Article Text |
id | pubmed-3998590 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39985902014-05-13 Bis[4-amino-N-(4-methylpyrimidin-2-yl-κN (3))benzenesulfonamidato-κN](2,2′-bipyridine-κ(2) N,N′)mercury(II) Hossain, G. M. Golzar Amoroso, A. J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete molecule of the title complex, [Hg(C(11)H(11)N(4)O(2)S)(2)(C(10)H(8)N(2))], is generated by crystallographic twofold symmetry, with the mercury cation lying on the rotation axis. The mercury coordination polyhedron can be described as tetrahedral (from the N,N′-bidenate bipyridine molecule and the sulfonamide N atoms of the sulfamerazine anions) or as squashed trigonal-prismatic, if two long (> 2.80 Å) Hg—N bonds to pyrimidine N atoms are included. The dihedral angle between the aromatic rings in the anion is 73.3 (2)°. In the crystal, N—H⋯(N,O) and N—H⋯N hydrogen bonds link the molecules into a three-dimensional network. International Union of Crystallography 2014-03-08 /pmc/articles/PMC3998590/ /pubmed/24826092 http://dx.doi.org/10.1107/S1600536814004760 Text en © Hossain and Amoroso 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hossain, G. M. Golzar Amoroso, A. J. Bis[4-amino-N-(4-methylpyrimidin-2-yl-κN (3))benzenesulfonamidato-κN](2,2′-bipyridine-κ(2) N,N′)mercury(II) |
title | Bis[4-amino-N-(4-methylpyrimidin-2-yl-κN
(3))benzenesulfonamidato-κN](2,2′-bipyridine-κ(2)
N,N′)mercury(II) |
title_full | Bis[4-amino-N-(4-methylpyrimidin-2-yl-κN
(3))benzenesulfonamidato-κN](2,2′-bipyridine-κ(2)
N,N′)mercury(II) |
title_fullStr | Bis[4-amino-N-(4-methylpyrimidin-2-yl-κN
(3))benzenesulfonamidato-κN](2,2′-bipyridine-κ(2)
N,N′)mercury(II) |
title_full_unstemmed | Bis[4-amino-N-(4-methylpyrimidin-2-yl-κN
(3))benzenesulfonamidato-κN](2,2′-bipyridine-κ(2)
N,N′)mercury(II) |
title_short | Bis[4-amino-N-(4-methylpyrimidin-2-yl-κN
(3))benzenesulfonamidato-κN](2,2′-bipyridine-κ(2)
N,N′)mercury(II) |
title_sort | bis[4-amino-n-(4-methylpyrimidin-2-yl-κn
(3))benzenesulfonamidato-κn](2,2′-bipyridine-κ(2)
n,n′)mercury(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998590/ https://www.ncbi.nlm.nih.gov/pubmed/24826092 http://dx.doi.org/10.1107/S1600536814004760 |
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