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[1,2-Bis(di­cyclo­hexyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane-2κ(2) P,P′]di-μ-chlorido-1:2κ(4) Cl:Cl-di­chlorido-1κ(2) Cl-dimercury(II)

The title compound, [Hg(2)Cl(4)(C(26)H(54)B(10)P(2))], was synthesized by the reaction of 1,2-bis­(di­cyclo­hexyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane with HgCl(2). Both Hg(II) atoms show a distorted tetra­hedral coordination geometry, provided by the two bridging chloride anions and the P a...

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Detalles Bibliográficos
Autor principal: Yang, Liguo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998597/
https://www.ncbi.nlm.nih.gov/pubmed/24826101
http://dx.doi.org/10.1107/S1600536814006096
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author Yang, Liguo
author_facet Yang, Liguo
author_sort Yang, Liguo
collection PubMed
description The title compound, [Hg(2)Cl(4)(C(26)H(54)B(10)P(2))], was synthesized by the reaction of 1,2-bis­(di­cyclo­hexyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane with HgCl(2). Both Hg(II) atoms show a distorted tetra­hedral coordination geometry, provided by the two bridging chloride anions and the P atoms of the diphosphanyl ligand for one metal atom, and by two bridging and two terminal chloride anions for the other. The five-membered HgP(2)C(2) chelate ring assumes an envelope conformation, with the Hg(II) atom displaced by 0.1650 (5) Å from the mean plane of the other four atoms (r.m.s. deviation = 0.002 Å). In the crystal, B—H⋯Cl interactions link the molecules, forming a supramolecular chain along the a-axis direction.
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spelling pubmed-39985972014-05-13 [1,2-Bis(di­cyclo­hexyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane-2κ(2) P,P′]di-μ-chlorido-1:2κ(4) Cl:Cl-di­chlorido-1κ(2) Cl-dimercury(II) Yang, Liguo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Hg(2)Cl(4)(C(26)H(54)B(10)P(2))], was synthesized by the reaction of 1,2-bis­(di­cyclo­hexyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane with HgCl(2). Both Hg(II) atoms show a distorted tetra­hedral coordination geometry, provided by the two bridging chloride anions and the P atoms of the diphosphanyl ligand for one metal atom, and by two bridging and two terminal chloride anions for the other. The five-membered HgP(2)C(2) chelate ring assumes an envelope conformation, with the Hg(II) atom displaced by 0.1650 (5) Å from the mean plane of the other four atoms (r.m.s. deviation = 0.002 Å). In the crystal, B—H⋯Cl interactions link the molecules, forming a supramolecular chain along the a-axis direction. International Union of Crystallography 2014-03-22 /pmc/articles/PMC3998597/ /pubmed/24826101 http://dx.doi.org/10.1107/S1600536814006096 Text en © Liguo Yang 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Liguo
[1,2-Bis(di­cyclo­hexyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane-2κ(2) P,P′]di-μ-chlorido-1:2κ(4) Cl:Cl-di­chlorido-1κ(2) Cl-dimercury(II)
title [1,2-Bis(di­cyclo­hexyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane-2κ(2) P,P′]di-μ-chlorido-1:2κ(4) Cl:Cl-di­chlorido-1κ(2) Cl-dimercury(II)
title_full [1,2-Bis(di­cyclo­hexyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane-2κ(2) P,P′]di-μ-chlorido-1:2κ(4) Cl:Cl-di­chlorido-1κ(2) Cl-dimercury(II)
title_fullStr [1,2-Bis(di­cyclo­hexyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane-2κ(2) P,P′]di-μ-chlorido-1:2κ(4) Cl:Cl-di­chlorido-1κ(2) Cl-dimercury(II)
title_full_unstemmed [1,2-Bis(di­cyclo­hexyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane-2κ(2) P,P′]di-μ-chlorido-1:2κ(4) Cl:Cl-di­chlorido-1κ(2) Cl-dimercury(II)
title_short [1,2-Bis(di­cyclo­hexyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane-2κ(2) P,P′]di-μ-chlorido-1:2κ(4) Cl:Cl-di­chlorido-1κ(2) Cl-dimercury(II)
title_sort [1,2-bis(di­cyclo­hexyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane-2κ(2) p,p′]di-μ-chlorido-1:2κ(4) cl:cl-di­chlorido-1κ(2) cl-dimercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998597/
https://www.ncbi.nlm.nih.gov/pubmed/24826101
http://dx.doi.org/10.1107/S1600536814006096
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