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[1,2-Bis(dicyclohexylphosphanyl)-1,2-dicarba-closo-dodecaborane-2κ(2) P,P′]di-μ-chlorido-1:2κ(4) Cl:Cl-dichlorido-1κ(2) Cl-dimercury(II)
The title compound, [Hg(2)Cl(4)(C(26)H(54)B(10)P(2))], was synthesized by the reaction of 1,2-bis(dicyclohexylphosphanyl)-1,2-dicarba-closo-dodecaborane with HgCl(2). Both Hg(II) atoms show a distorted tetrahedral coordination geometry, provided by the two bridging chloride anions and the P a...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998597/ https://www.ncbi.nlm.nih.gov/pubmed/24826101 http://dx.doi.org/10.1107/S1600536814006096 |
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author | Yang, Liguo |
author_facet | Yang, Liguo |
author_sort | Yang, Liguo |
collection | PubMed |
description | The title compound, [Hg(2)Cl(4)(C(26)H(54)B(10)P(2))], was synthesized by the reaction of 1,2-bis(dicyclohexylphosphanyl)-1,2-dicarba-closo-dodecaborane with HgCl(2). Both Hg(II) atoms show a distorted tetrahedral coordination geometry, provided by the two bridging chloride anions and the P atoms of the diphosphanyl ligand for one metal atom, and by two bridging and two terminal chloride anions for the other. The five-membered HgP(2)C(2) chelate ring assumes an envelope conformation, with the Hg(II) atom displaced by 0.1650 (5) Å from the mean plane of the other four atoms (r.m.s. deviation = 0.002 Å). In the crystal, B—H⋯Cl interactions link the molecules, forming a supramolecular chain along the a-axis direction. |
format | Online Article Text |
id | pubmed-3998597 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39985972014-05-13 [1,2-Bis(dicyclohexylphosphanyl)-1,2-dicarba-closo-dodecaborane-2κ(2) P,P′]di-μ-chlorido-1:2κ(4) Cl:Cl-dichlorido-1κ(2) Cl-dimercury(II) Yang, Liguo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Hg(2)Cl(4)(C(26)H(54)B(10)P(2))], was synthesized by the reaction of 1,2-bis(dicyclohexylphosphanyl)-1,2-dicarba-closo-dodecaborane with HgCl(2). Both Hg(II) atoms show a distorted tetrahedral coordination geometry, provided by the two bridging chloride anions and the P atoms of the diphosphanyl ligand for one metal atom, and by two bridging and two terminal chloride anions for the other. The five-membered HgP(2)C(2) chelate ring assumes an envelope conformation, with the Hg(II) atom displaced by 0.1650 (5) Å from the mean plane of the other four atoms (r.m.s. deviation = 0.002 Å). In the crystal, B—H⋯Cl interactions link the molecules, forming a supramolecular chain along the a-axis direction. International Union of Crystallography 2014-03-22 /pmc/articles/PMC3998597/ /pubmed/24826101 http://dx.doi.org/10.1107/S1600536814006096 Text en © Liguo Yang 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yang, Liguo [1,2-Bis(dicyclohexylphosphanyl)-1,2-dicarba-closo-dodecaborane-2κ(2) P,P′]di-μ-chlorido-1:2κ(4) Cl:Cl-dichlorido-1κ(2) Cl-dimercury(II) |
title | [1,2-Bis(dicyclohexylphosphanyl)-1,2-dicarba-closo-dodecaborane-2κ(2)
P,P′]di-μ-chlorido-1:2κ(4)
Cl:Cl-dichlorido-1κ(2)
Cl-dimercury(II) |
title_full | [1,2-Bis(dicyclohexylphosphanyl)-1,2-dicarba-closo-dodecaborane-2κ(2)
P,P′]di-μ-chlorido-1:2κ(4)
Cl:Cl-dichlorido-1κ(2)
Cl-dimercury(II) |
title_fullStr | [1,2-Bis(dicyclohexylphosphanyl)-1,2-dicarba-closo-dodecaborane-2κ(2)
P,P′]di-μ-chlorido-1:2κ(4)
Cl:Cl-dichlorido-1κ(2)
Cl-dimercury(II) |
title_full_unstemmed | [1,2-Bis(dicyclohexylphosphanyl)-1,2-dicarba-closo-dodecaborane-2κ(2)
P,P′]di-μ-chlorido-1:2κ(4)
Cl:Cl-dichlorido-1κ(2)
Cl-dimercury(II) |
title_short | [1,2-Bis(dicyclohexylphosphanyl)-1,2-dicarba-closo-dodecaborane-2κ(2)
P,P′]di-μ-chlorido-1:2κ(4)
Cl:Cl-dichlorido-1κ(2)
Cl-dimercury(II) |
title_sort | [1,2-bis(dicyclohexylphosphanyl)-1,2-dicarba-closo-dodecaborane-2κ(2)
p,p′]di-μ-chlorido-1:2κ(4)
cl:cl-dichlorido-1κ(2)
cl-dimercury(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998597/ https://www.ncbi.nlm.nih.gov/pubmed/24826101 http://dx.doi.org/10.1107/S1600536814006096 |
work_keys_str_mv | AT yangliguo 12bisdicyclohexylphosphanyl12dicarbaclosododecaborane2k2ppdimchlorido12k4clcldichlorido1k2cldimercuryii |