5-Bromo-3-ethyl­sulfinyl-7-methyl-2-(4-methyl­phen­yl)-1-benzo­furan

In the title compound, C(18)H(17)BrO(2)S, the dihedral angle between the mean planes of the benzo­furan and 4-methyl­phenyl rings is 14.54 (5)°. In the crystal, mol­ecules are linked via pairs of π–π inter­actions between the benzene and 4-methyl­phenyl rings, with centroid–centroid distances of 3.8...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Lee, Uk
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998609/
https://www.ncbi.nlm.nih.gov/pubmed/24826160
http://dx.doi.org/10.1107/S1600536814005844
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author Choi, Hong Dae
Seo, Pil Ja
Lee, Uk
author_facet Choi, Hong Dae
Seo, Pil Ja
Lee, Uk
author_sort Choi, Hong Dae
collection PubMed
description In the title compound, C(18)H(17)BrO(2)S, the dihedral angle between the mean planes of the benzo­furan and 4-methyl­phenyl rings is 14.54 (5)°. In the crystal, mol­ecules are linked via pairs of π–π inter­actions between the benzene and 4-methyl­phenyl rings, with centroid–centroid distances of 3.811 (3) and 3.755 (3) Å. A similar inter­action is found between the furan and 4-methyl­phenyl rings, with a centroid–centroid distance of 3.866 (3) Å between neighbouring mol­ecules. The mol­ecules are stacked along the a-axis direction. In addition, a short Br⋯O contact distance of 3.128 (2) Å is observed between inversion-related dimers.
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spelling pubmed-39986092014-05-13 5-Bromo-3-ethyl­sulfinyl-7-methyl-2-(4-methyl­phen­yl)-1-benzo­furan Choi, Hong Dae Seo, Pil Ja Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(17)BrO(2)S, the dihedral angle between the mean planes of the benzo­furan and 4-methyl­phenyl rings is 14.54 (5)°. In the crystal, mol­ecules are linked via pairs of π–π inter­actions between the benzene and 4-methyl­phenyl rings, with centroid–centroid distances of 3.811 (3) and 3.755 (3) Å. A similar inter­action is found between the furan and 4-methyl­phenyl rings, with a centroid–centroid distance of 3.866 (3) Å between neighbouring mol­ecules. The mol­ecules are stacked along the a-axis direction. In addition, a short Br⋯O contact distance of 3.128 (2) Å is observed between inversion-related dimers. International Union of Crystallography 2014-03-22 /pmc/articles/PMC3998609/ /pubmed/24826160 http://dx.doi.org/10.1107/S1600536814005844 Text en © Choi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Choi, Hong Dae
Seo, Pil Ja
Lee, Uk
5-Bromo-3-ethyl­sulfinyl-7-methyl-2-(4-methyl­phen­yl)-1-benzo­furan
title 5-Bromo-3-ethyl­sulfinyl-7-methyl-2-(4-methyl­phen­yl)-1-benzo­furan
title_full 5-Bromo-3-ethyl­sulfinyl-7-methyl-2-(4-methyl­phen­yl)-1-benzo­furan
title_fullStr 5-Bromo-3-ethyl­sulfinyl-7-methyl-2-(4-methyl­phen­yl)-1-benzo­furan
title_full_unstemmed 5-Bromo-3-ethyl­sulfinyl-7-methyl-2-(4-methyl­phen­yl)-1-benzo­furan
title_short 5-Bromo-3-ethyl­sulfinyl-7-methyl-2-(4-methyl­phen­yl)-1-benzo­furan
title_sort 5-bromo-3-ethyl­sulfinyl-7-methyl-2-(4-methyl­phen­yl)-1-benzo­furan
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998609/
https://www.ncbi.nlm.nih.gov/pubmed/24826160
http://dx.doi.org/10.1107/S1600536814005844
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AT leeuk 5bromo3ethylsulfinyl7methyl24methylphenyl1benzofuran

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