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Bis{2-[(pyridin-2-yl)methylideneamino]benzoato-κ(3) N,N′,O}chromium(III) nitrate monohydrate
The title complex salt hydrate, [Cr(C(13)H(9)N(2)O(2))(2)]NO(3)·H(2)O, comprises discrete cations, nitrate anions and solvent water molecules. The Cr(III) atom is octahedrally coordinated by two anionic Schiff base ligands with the O atoms being cis. The two ligands differ significantly with dihed...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998614/ https://www.ncbi.nlm.nih.gov/pubmed/24826098 http://dx.doi.org/10.1107/S1600536814005649 |
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| author | Buvaylo, Elena A. Kokozay, Vladimir N. Vassilyeva, Olga Yu. Skelton, Brian W. |
| author_facet | Buvaylo, Elena A. Kokozay, Vladimir N. Vassilyeva, Olga Yu. Skelton, Brian W. |
| author_sort | Buvaylo, Elena A. |
| collection | PubMed |
| description | The title complex salt hydrate, [Cr(C(13)H(9)N(2)O(2))(2)]NO(3)·H(2)O, comprises discrete cations, nitrate anions and solvent water molecules. The Cr(III) atom is octahedrally coordinated by two anionic Schiff base ligands with the O atoms being cis. The two ligands differ significantly with dihedral angles between the pyridine and benzene rings of 4.8 (2) and 24.9 (2)°. The nitrate anion and solvent water molecule were modelled as being disordered, with the major components having site-occupancy values of 0.856 (14) and 0.727 (16), respectively. The crystal is built of alternating layers of cations and of anions plus water molecules, stacked along the c axis. |
| format | Online Article Text |
| id | pubmed-3998614 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-39986142014-05-13 Bis{2-[(pyridin-2-yl)methylideneamino]benzoato-κ(3) N,N′,O}chromium(III) nitrate monohydrate Buvaylo, Elena A. Kokozay, Vladimir N. Vassilyeva, Olga Yu. Skelton, Brian W. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex salt hydrate, [Cr(C(13)H(9)N(2)O(2))(2)]NO(3)·H(2)O, comprises discrete cations, nitrate anions and solvent water molecules. The Cr(III) atom is octahedrally coordinated by two anionic Schiff base ligands with the O atoms being cis. The two ligands differ significantly with dihedral angles between the pyridine and benzene rings of 4.8 (2) and 24.9 (2)°. The nitrate anion and solvent water molecule were modelled as being disordered, with the major components having site-occupancy values of 0.856 (14) and 0.727 (16), respectively. The crystal is built of alternating layers of cations and of anions plus water molecules, stacked along the c axis. International Union of Crystallography 2014-03-15 /pmc/articles/PMC3998614/ /pubmed/24826098 http://dx.doi.org/10.1107/S1600536814005649 Text en © Buvaylo et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Buvaylo, Elena A. Kokozay, Vladimir N. Vassilyeva, Olga Yu. Skelton, Brian W. Bis{2-[(pyridin-2-yl)methylideneamino]benzoato-κ(3) N,N′,O}chromium(III) nitrate monohydrate |
| title | Bis{2-[(pyridin-2-yl)methylideneamino]benzoato-κ(3)
N,N′,O}chromium(III) nitrate monohydrate |
| title_full | Bis{2-[(pyridin-2-yl)methylideneamino]benzoato-κ(3)
N,N′,O}chromium(III) nitrate monohydrate |
| title_fullStr | Bis{2-[(pyridin-2-yl)methylideneamino]benzoato-κ(3)
N,N′,O}chromium(III) nitrate monohydrate |
| title_full_unstemmed | Bis{2-[(pyridin-2-yl)methylideneamino]benzoato-κ(3)
N,N′,O}chromium(III) nitrate monohydrate |
| title_short | Bis{2-[(pyridin-2-yl)methylideneamino]benzoato-κ(3)
N,N′,O}chromium(III) nitrate monohydrate |
| title_sort | bis{2-[(pyridin-2-yl)methylideneamino]benzoato-κ(3)
n,n′,o}chromium(iii) nitrate monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998614/ https://www.ncbi.nlm.nih.gov/pubmed/24826098 http://dx.doi.org/10.1107/S1600536814005649 |
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