Cargando…

2-Chloro-N-(2-chloro­benzo­yl)-N-(2-ethyl-4-oxo-3,4-di­hydro­quinazolin-3-yl)benzamide

In the title compound, C(24)H(17)Cl(2)N(3)O(3), the quinazolinone ring system is close to planar (r.m.s. deviation = 0.0132 Å), with the imide unit almost perpendicular to it, subtending a dihedral angle of 89.1 (1)°. However, the imide unit itself is not planar, the dihedral angle between the two O...

Descripción completa

Detalles Bibliográficos
Autores principales: Bakare, Oladapo, Thompson, Candice, Brandy, Yakini, Butcher, Ray J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998615/
https://www.ncbi.nlm.nih.gov/pubmed/24826190
http://dx.doi.org/10.1107/S1600536814006035
_version_ 1782313400268750848
author Bakare, Oladapo
Thompson, Candice
Brandy, Yakini
Butcher, Ray J.
author_facet Bakare, Oladapo
Thompson, Candice
Brandy, Yakini
Butcher, Ray J.
author_sort Bakare, Oladapo
collection PubMed
description In the title compound, C(24)H(17)Cl(2)N(3)O(3), the quinazolinone ring system is close to planar (r.m.s. deviation = 0.0132 Å), with the imide unit almost perpendicular to it, subtending a dihedral angle of 89.1 (1)°. However, the imide unit itself is not planar, the dihedral angle between the two O=C—N components being 34.6 (1)°. The dihedral angle between the two chlorobenzene rings is 40.50 (7)°, while the angles between these rings and the imide moiety are 54.6 (1) and 58.2 (1)°, respectively. The dihedral angles between the 2-chloro­phenyl rings and the quinazolinone ring system are 48.77 (5) and 32.92 (7)° for rings A and B, respectively. In the crystal, weak C—H⋯O inter­actions link the mol­ecules into a three-dimensional array.
format Online
Article
Text
id pubmed-3998615
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-39986152014-05-13 2-Chloro-N-(2-chloro­benzo­yl)-N-(2-ethyl-4-oxo-3,4-di­hydro­quinazolin-3-yl)benzamide Bakare, Oladapo Thompson, Candice Brandy, Yakini Butcher, Ray J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(17)Cl(2)N(3)O(3), the quinazolinone ring system is close to planar (r.m.s. deviation = 0.0132 Å), with the imide unit almost perpendicular to it, subtending a dihedral angle of 89.1 (1)°. However, the imide unit itself is not planar, the dihedral angle between the two O=C—N components being 34.6 (1)°. The dihedral angle between the two chlorobenzene rings is 40.50 (7)°, while the angles between these rings and the imide moiety are 54.6 (1) and 58.2 (1)°, respectively. The dihedral angles between the 2-chloro­phenyl rings and the quinazolinone ring system are 48.77 (5) and 32.92 (7)° for rings A and B, respectively. In the crystal, weak C—H⋯O inter­actions link the mol­ecules into a three-dimensional array. International Union of Crystallography 2014-03-29 /pmc/articles/PMC3998615/ /pubmed/24826190 http://dx.doi.org/10.1107/S1600536814006035 Text en © Bakare et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bakare, Oladapo
Thompson, Candice
Brandy, Yakini
Butcher, Ray J.
2-Chloro-N-(2-chloro­benzo­yl)-N-(2-ethyl-4-oxo-3,4-di­hydro­quinazolin-3-yl)benzamide
title 2-Chloro-N-(2-chloro­benzo­yl)-N-(2-ethyl-4-oxo-3,4-di­hydro­quinazolin-3-yl)benzamide
title_full 2-Chloro-N-(2-chloro­benzo­yl)-N-(2-ethyl-4-oxo-3,4-di­hydro­quinazolin-3-yl)benzamide
title_fullStr 2-Chloro-N-(2-chloro­benzo­yl)-N-(2-ethyl-4-oxo-3,4-di­hydro­quinazolin-3-yl)benzamide
title_full_unstemmed 2-Chloro-N-(2-chloro­benzo­yl)-N-(2-ethyl-4-oxo-3,4-di­hydro­quinazolin-3-yl)benzamide
title_short 2-Chloro-N-(2-chloro­benzo­yl)-N-(2-ethyl-4-oxo-3,4-di­hydro­quinazolin-3-yl)benzamide
title_sort 2-chloro-n-(2-chloro­benzo­yl)-n-(2-ethyl-4-oxo-3,4-di­hydro­quinazolin-3-yl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998615/
https://www.ncbi.nlm.nih.gov/pubmed/24826190
http://dx.doi.org/10.1107/S1600536814006035
work_keys_str_mv AT bakareoladapo 2chloron2chlorobenzoyln2ethyl4oxo34dihydroquinazolin3ylbenzamide
AT thompsoncandice 2chloron2chlorobenzoyln2ethyl4oxo34dihydroquinazolin3ylbenzamide
AT brandyyakini 2chloron2chlorobenzoyln2ethyl4oxo34dihydroquinazolin3ylbenzamide
AT butcherrayj 2chloron2chlorobenzoyln2ethyl4oxo34dihydroquinazolin3ylbenzamide