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Hepta­carbonyl­bis­(μ-propane-1,3-di­thiol­ato)triiron(I,II)(2 Fe—Fe)

The trinuclear title compound, [Fe(3)(C(3)H(6)S(2))(2)(CO)(7)], is a mixed-valent Fe(I)/Fe(II) complex and crystallizes with two mol­ecules of similar configuration in the asymmetric unit. The three Fe atoms in each mol­ecule display a bent arrangement [Fe—Fe—Fe = 156.22 (4) and 157.06 (3)°]. Both o...

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Autores principales: Hu, Mingqiang, Ma, Chengbing, Wen, Huimin, Cui, Honghua, Chen, Changneng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998616/
https://www.ncbi.nlm.nih.gov/pubmed/24826090
http://dx.doi.org/10.1107/S1600536814004619
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author Hu, Mingqiang
Ma, Chengbing
Wen, Huimin
Cui, Honghua
Chen, Changneng
author_facet Hu, Mingqiang
Ma, Chengbing
Wen, Huimin
Cui, Honghua
Chen, Changneng
author_sort Hu, Mingqiang
collection PubMed
description The trinuclear title compound, [Fe(3)(C(3)H(6)S(2))(2)(CO)(7)], is a mixed-valent Fe(I)/Fe(II) complex and crystallizes with two mol­ecules of similar configuration in the asymmetric unit. The three Fe atoms in each mol­ecule display a bent arrangement [Fe—Fe—Fe = 156.22 (4) and 157.06 (3)°]. Both outer Fe(I) atoms are six-coordinated in a distorted ocahedral coordination geometry defined by the bridging Fe(II) atom, three carbonyl C atoms and two bridging S atoms. The coordination number of the central Fe(II) atom is seven and includes bonding to the two outer Fe(I) atoms, four bridging S atoms and one carbonyl C atom. The resulting coordination polyhedron might be described as a highly distorted monocapped trigonal prism. In the crystal packing, the mol­ecules exhibit a chain-like arrangement parallel to [100] and [001], and the resulting layers are stacked along [010]. The cohesion of the structure is dominated by van der Waals inter­actions.
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spelling pubmed-39986162014-05-13 Hepta­carbonyl­bis­(μ-propane-1,3-di­thiol­ato)triiron(I,II)(2 Fe—Fe) Hu, Mingqiang Ma, Chengbing Wen, Huimin Cui, Honghua Chen, Changneng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The trinuclear title compound, [Fe(3)(C(3)H(6)S(2))(2)(CO)(7)], is a mixed-valent Fe(I)/Fe(II) complex and crystallizes with two mol­ecules of similar configuration in the asymmetric unit. The three Fe atoms in each mol­ecule display a bent arrangement [Fe—Fe—Fe = 156.22 (4) and 157.06 (3)°]. Both outer Fe(I) atoms are six-coordinated in a distorted ocahedral coordination geometry defined by the bridging Fe(II) atom, three carbonyl C atoms and two bridging S atoms. The coordination number of the central Fe(II) atom is seven and includes bonding to the two outer Fe(I) atoms, four bridging S atoms and one carbonyl C atom. The resulting coordination polyhedron might be described as a highly distorted monocapped trigonal prism. In the crystal packing, the mol­ecules exhibit a chain-like arrangement parallel to [100] and [001], and the resulting layers are stacked along [010]. The cohesion of the structure is dominated by van der Waals inter­actions. International Union of Crystallography 2014-03-08 /pmc/articles/PMC3998616/ /pubmed/24826090 http://dx.doi.org/10.1107/S1600536814004619 Text en © Hu et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hu, Mingqiang
Ma, Chengbing
Wen, Huimin
Cui, Honghua
Chen, Changneng
Hepta­carbonyl­bis­(μ-propane-1,3-di­thiol­ato)triiron(I,II)(2 Fe—Fe)
title Hepta­carbonyl­bis­(μ-propane-1,3-di­thiol­ato)triiron(I,II)(2 Fe—Fe)
title_full Hepta­carbonyl­bis­(μ-propane-1,3-di­thiol­ato)triiron(I,II)(2 Fe—Fe)
title_fullStr Hepta­carbonyl­bis­(μ-propane-1,3-di­thiol­ato)triiron(I,II)(2 Fe—Fe)
title_full_unstemmed Hepta­carbonyl­bis­(μ-propane-1,3-di­thiol­ato)triiron(I,II)(2 Fe—Fe)
title_short Hepta­carbonyl­bis­(μ-propane-1,3-di­thiol­ato)triiron(I,II)(2 Fe—Fe)
title_sort hepta­carbonyl­bis­(μ-propane-1,3-di­thiol­ato)triiron(i,ii)(2 fe—fe)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998616/
https://www.ncbi.nlm.nih.gov/pubmed/24826090
http://dx.doi.org/10.1107/S1600536814004619
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