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catena-Poly[[di-tert-butyl­tin(IV)]-μ-oxalato]

The title compound, [Sn(C(4)H(9))(2)(C(2)O(4))](n), an unexpected side product in the reaction of di-tert-butyl­tin(IV) oxide with nitric acid, represents the first diorganotin(IV) oxalate to be structurally characterized. The Sn(IV) atom of the one-dimensional coordination polymer is located on a m...

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Autores principales: Reichelt, Martin, Reuter, Hans
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998617/
https://www.ncbi.nlm.nih.gov/pubmed/24826096
http://dx.doi.org/10.1107/S160053681400539X
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author Reichelt, Martin
Reuter, Hans
author_facet Reichelt, Martin
Reuter, Hans
author_sort Reichelt, Martin
collection PubMed
description The title compound, [Sn(C(4)H(9))(2)(C(2)O(4))](n), an unexpected side product in the reaction of di-tert-butyl­tin(IV) oxide with nitric acid, represents the first diorganotin(IV) oxalate to be structurally characterized. The Sn(IV) atom of the one-dimensional coordination polymer is located on a mirror plane and is coordinated by two chelating oxalate ions with two rather different Sn—O bond lengths of 2.150 (1) and 2.425 (1) Å, and two t-butyl groups with Sn—C bond lengths of 2.186 (2) and 2.190 (2) Å. The coordination polyhedron around the Sn(IV) atom is a distorted tetra­gonal disphenoid. The centrosymmetric oxalate ion also has an asymmetric coordination geometry, as reflected by the two slightly different C—O bond lengths of 1.242 (2) and 1.269 (2) Å. The chains of the polymer propagate along the b-axis direction. Only van der Waals inter­actions are observed between the chains.
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spelling pubmed-39986172014-05-13 catena-Poly[[di-tert-butyl­tin(IV)]-μ-oxalato] Reichelt, Martin Reuter, Hans Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(C(4)H(9))(2)(C(2)O(4))](n), an unexpected side product in the reaction of di-tert-butyl­tin(IV) oxide with nitric acid, represents the first diorganotin(IV) oxalate to be structurally characterized. The Sn(IV) atom of the one-dimensional coordination polymer is located on a mirror plane and is coordinated by two chelating oxalate ions with two rather different Sn—O bond lengths of 2.150 (1) and 2.425 (1) Å, and two t-butyl groups with Sn—C bond lengths of 2.186 (2) and 2.190 (2) Å. The coordination polyhedron around the Sn(IV) atom is a distorted tetra­gonal disphenoid. The centrosymmetric oxalate ion also has an asymmetric coordination geometry, as reflected by the two slightly different C—O bond lengths of 1.242 (2) and 1.269 (2) Å. The chains of the polymer propagate along the b-axis direction. Only van der Waals inter­actions are observed between the chains. International Union of Crystallography 2014-03-15 /pmc/articles/PMC3998617/ /pubmed/24826096 http://dx.doi.org/10.1107/S160053681400539X Text en © Reichelt and Reuter 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Reichelt, Martin
Reuter, Hans
catena-Poly[[di-tert-butyl­tin(IV)]-μ-oxalato]
title catena-Poly[[di-tert-butyl­tin(IV)]-μ-oxalato]
title_full catena-Poly[[di-tert-butyl­tin(IV)]-μ-oxalato]
title_fullStr catena-Poly[[di-tert-butyl­tin(IV)]-μ-oxalato]
title_full_unstemmed catena-Poly[[di-tert-butyl­tin(IV)]-μ-oxalato]
title_short catena-Poly[[di-tert-butyl­tin(IV)]-μ-oxalato]
title_sort catena-poly[[di-tert-butyl­tin(iv)]-μ-oxalato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998617/
https://www.ncbi.nlm.nih.gov/pubmed/24826096
http://dx.doi.org/10.1107/S160053681400539X
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