4-tert-Butyl­pyridinium chloride–4,4′-(propane-2,2-di­yl)bis­(2,6-di­methyl­phenol)–toluene (2/2/1)

In the title solvated salt, C(9)H(14)N(+)·Cl(−)·C(19)H(24)O(2)·0.5C(7)H(7), two mol­ecules of 4,4′-(propane-2,2-di­yl)bis­(2,6-di­methyl­phenol) are linked via O—H⋯Cl hydrogen bonds to two chloride ions, each of which is also engaged in N—H⋯Cl hydrogen bonding to a 4-tert-butyl­pyridinium cation, gi...

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Detalles Bibliográficos
Autores principales: Nielson, Alastair J., Waters, Joyce M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998618/
https://www.ncbi.nlm.nih.gov/pubmed/24826127
http://dx.doi.org/10.1107/S1600536814004942
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author Nielson, Alastair J.
Waters, Joyce M.
author_facet Nielson, Alastair J.
Waters, Joyce M.
author_sort Nielson, Alastair J.
collection PubMed
description In the title solvated salt, C(9)H(14)N(+)·Cl(−)·C(19)H(24)O(2)·0.5C(7)H(7), two mol­ecules of 4,4′-(propane-2,2-di­yl)bis­(2,6-di­methyl­phenol) are linked via O—H⋯Cl hydrogen bonds to two chloride ions, each of which is also engaged in N—H⋯Cl hydrogen bonding to a 4-tert-butyl­pyridinium cation, giving a cyclic hydrogen-bonded entity centred at 1/2, 1/2, 1/2. The toluene solvent mol­ecule resides in the lattice and resides on an inversion centre; the disorder of the methyl group requires it to have a site-occupancy factor of 0.5. No crystal packing channels are observed.
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spelling pubmed-39986182014-05-13 4-tert-Butyl­pyridinium chloride–4,4′-(propane-2,2-di­yl)bis­(2,6-di­methyl­phenol)–toluene (2/2/1) Nielson, Alastair J. Waters, Joyce M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title solvated salt, C(9)H(14)N(+)·Cl(−)·C(19)H(24)O(2)·0.5C(7)H(7), two mol­ecules of 4,4′-(propane-2,2-di­yl)bis­(2,6-di­methyl­phenol) are linked via O—H⋯Cl hydrogen bonds to two chloride ions, each of which is also engaged in N—H⋯Cl hydrogen bonding to a 4-tert-butyl­pyridinium cation, giving a cyclic hydrogen-bonded entity centred at 1/2, 1/2, 1/2. The toluene solvent mol­ecule resides in the lattice and resides on an inversion centre; the disorder of the methyl group requires it to have a site-occupancy factor of 0.5. No crystal packing channels are observed. International Union of Crystallography 2014-03-12 /pmc/articles/PMC3998618/ /pubmed/24826127 http://dx.doi.org/10.1107/S1600536814004942 Text en © Nielson and Waters 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nielson, Alastair J.
Waters, Joyce M.
4-tert-Butyl­pyridinium chloride–4,4′-(propane-2,2-di­yl)bis­(2,6-di­methyl­phenol)–toluene (2/2/1)
title 4-tert-Butyl­pyridinium chloride–4,4′-(propane-2,2-di­yl)bis­(2,6-di­methyl­phenol)–toluene (2/2/1)
title_full 4-tert-Butyl­pyridinium chloride–4,4′-(propane-2,2-di­yl)bis­(2,6-di­methyl­phenol)–toluene (2/2/1)
title_fullStr 4-tert-Butyl­pyridinium chloride–4,4′-(propane-2,2-di­yl)bis­(2,6-di­methyl­phenol)–toluene (2/2/1)
title_full_unstemmed 4-tert-Butyl­pyridinium chloride–4,4′-(propane-2,2-di­yl)bis­(2,6-di­methyl­phenol)–toluene (2/2/1)
title_short 4-tert-Butyl­pyridinium chloride–4,4′-(propane-2,2-di­yl)bis­(2,6-di­methyl­phenol)–toluene (2/2/1)
title_sort 4-tert-butyl­pyridinium chloride–4,4′-(propane-2,2-di­yl)bis­(2,6-di­methyl­phenol)–toluene (2/2/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998618/
https://www.ncbi.nlm.nih.gov/pubmed/24826127
http://dx.doi.org/10.1107/S1600536814004942
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AT watersjoycem 4tertbutylpyridiniumchloride44propane22diylbis26dimethylphenoltoluene221

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