N-(2-Chloro­eth­yl)morpholine-4-carbox­amide

The title compound, C(7)H(13)ClN(2)O(2), synthesized by the reaction of 2-chloro­ethyl iso­cyanate and morpholine, crystallizes with four molecules in the asymmetric unit, which have similar conformations and comprise two pairs each related by approximate non-crystallographic inversion centres. Two...

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Detalles Bibliográficos
Autores principales: Ujam, Oguejiofo T., Asegbeloyin, Jonnie N., Nicholson, Brian K., Ukoha, Pius O., Ukwueze, Nkechi N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998621/
https://www.ncbi.nlm.nih.gov/pubmed/24826162
http://dx.doi.org/10.1107/S1600536814005832
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author Ujam, Oguejiofo T.
Asegbeloyin, Jonnie N.
Nicholson, Brian K.
Ukoha, Pius O.
Ukwueze, Nkechi N.
author_facet Ujam, Oguejiofo T.
Asegbeloyin, Jonnie N.
Nicholson, Brian K.
Ukoha, Pius O.
Ukwueze, Nkechi N.
author_sort Ujam, Oguejiofo T.
collection PubMed
description The title compound, C(7)H(13)ClN(2)O(2), synthesized by the reaction of 2-chloro­ethyl iso­cyanate and morpholine, crystallizes with four molecules in the asymmetric unit, which have similar conformations and comprise two pairs each related by approximate non-crystallographic inversion centres. Two of them have a modest orientational disorder of the 2-chloro­ethyl fragments [occupancy ratio of 0.778 (4):0.222 (4)]. In the crystal, mol­ecules are linked by N—H⋯O=C hydrogen bonds, forming three crystallographically different kinds of infinite hydrogen-bonded chains extending along [001].
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spelling pubmed-39986212014-05-13 N-(2-Chloro­eth­yl)morpholine-4-carbox­amide Ujam, Oguejiofo T. Asegbeloyin, Jonnie N. Nicholson, Brian K. Ukoha, Pius O. Ukwueze, Nkechi N. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(7)H(13)ClN(2)O(2), synthesized by the reaction of 2-chloro­ethyl iso­cyanate and morpholine, crystallizes with four molecules in the asymmetric unit, which have similar conformations and comprise two pairs each related by approximate non-crystallographic inversion centres. Two of them have a modest orientational disorder of the 2-chloro­ethyl fragments [occupancy ratio of 0.778 (4):0.222 (4)]. In the crystal, mol­ecules are linked by N—H⋯O=C hydrogen bonds, forming three crystallographically different kinds of infinite hydrogen-bonded chains extending along [001]. International Union of Crystallography 2014-03-22 /pmc/articles/PMC3998621/ /pubmed/24826162 http://dx.doi.org/10.1107/S1600536814005832 Text en © Ujam et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ujam, Oguejiofo T.
Asegbeloyin, Jonnie N.
Nicholson, Brian K.
Ukoha, Pius O.
Ukwueze, Nkechi N.
N-(2-Chloro­eth­yl)morpholine-4-carbox­amide
title N-(2-Chloro­eth­yl)morpholine-4-carbox­amide
title_full N-(2-Chloro­eth­yl)morpholine-4-carbox­amide
title_fullStr N-(2-Chloro­eth­yl)morpholine-4-carbox­amide
title_full_unstemmed N-(2-Chloro­eth­yl)morpholine-4-carbox­amide
title_short N-(2-Chloro­eth­yl)morpholine-4-carbox­amide
title_sort n-(2-chloro­eth­yl)morpholine-4-carbox­amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998621/
https://www.ncbi.nlm.nih.gov/pubmed/24826162
http://dx.doi.org/10.1107/S1600536814005832
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AT ukohapiuso n2chloroethylmorpholine4carboxamide
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