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Di­chlorido­[N-(N,N-di­methyl­carbamimido­yl)-N′,N′,4-tri­methyl­benzohydrazonamide]­platinum(II) nitro­methane hemisolvate

In the title compound, [PtCl(2)(C(13)H(21)N(5))]·0.5CH(3)NO(2), the Pt(II) atom is coordinated in a slightly distorted square-planar geometry by two Cl atoms and two N atoms of the bidentate ligand. The (1,3,5-tri­aza­penta­diene)Pt(II) metalla ring is slightly bent and does not conjugate with the a...

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Detalles Bibliográficos
Autores principales: Bolotin, Dmitrii S., Bokach, Nadezha A., Haukka, Matti
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998624/
https://www.ncbi.nlm.nih.gov/pubmed/24826095
http://dx.doi.org/10.1107/S1600536814003894
Descripción
Sumario:In the title compound, [PtCl(2)(C(13)H(21)N(5))]·0.5CH(3)NO(2), the Pt(II) atom is coordinated in a slightly distorted square-planar geometry by two Cl atoms and two N atoms of the bidentate ligand. The (1,3,5-tri­aza­penta­diene)Pt(II) metalla ring is slightly bent and does not conjugate with the aromatic ring. In the crystal, N—H⋯Cl hydrogen bonds link the complex mol­ecules, forming chains along [001]. The nitromethane solvent molecule shows half-occupancy and is disordered over two sets of sites about an inversion centre.