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Dichlorido[N-(N,N-dimethylcarbamimidoyl)-N′,N′,4-trimethylbenzohydrazonamide]platinum(II) nitromethane hemisolvate
In the title compound, [PtCl(2)(C(13)H(21)N(5))]·0.5CH(3)NO(2), the Pt(II) atom is coordinated in a slightly distorted square-planar geometry by two Cl atoms and two N atoms of the bidentate ligand. The (1,3,5-triazapentadiene)Pt(II) metalla ring is slightly bent and does not conjugate with the a...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998624/ https://www.ncbi.nlm.nih.gov/pubmed/24826095 http://dx.doi.org/10.1107/S1600536814003894 |
Sumario: | In the title compound, [PtCl(2)(C(13)H(21)N(5))]·0.5CH(3)NO(2), the Pt(II) atom is coordinated in a slightly distorted square-planar geometry by two Cl atoms and two N atoms of the bidentate ligand. The (1,3,5-triazapentadiene)Pt(II) metalla ring is slightly bent and does not conjugate with the aromatic ring. In the crystal, N—H⋯Cl hydrogen bonds link the complex molecules, forming chains along [001]. The nitromethane solvent molecule shows half-occupancy and is disordered over two sets of sites about an inversion centre. |
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