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m-Xylylenediaminium dinitrate

The asymmetric unit of the title salt, C(8)H(14)N(2) (2+)·2NO(3) (−), contains two independent dications and four independent nitrate anions. The crystal structure consists of discrete nitrate ions, three of which stack in layers parallel to (001) at z = 0 and 0.5. These layers are connected via m-x...

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Detalles Bibliográficos
Autores principales: Gatfaoui, Sofian, Dhaouadi, Hassouna, Roisnel, Thierry, Rzaigui, Mohamed, Marouani, Houda
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998625/
https://www.ncbi.nlm.nih.gov/pubmed/24826118
http://dx.doi.org/10.1107/S1600536814004620
Descripción
Sumario:The asymmetric unit of the title salt, C(8)H(14)N(2) (2+)·2NO(3) (−), contains two independent dications and four independent nitrate anions. The crystal structure consists of discrete nitrate ions, three of which stack in layers parallel to (001) at z = 0 and 0.5. These layers are connected via m-xylylenediaminium dications. The fourth anion is sandwiched by the two independent organic cations in the asymmetric unit. In the crystal, the ions are connected by a large number of bifurcated and non-bifurcated N—H⋯O(O) hydrogen bonds, forming sheets parallel to (100). These sheets are connected by C—H⋯O hydrogen bonds, forming a three-dimensional network.