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m-Xylylenediaminium dinitrate
The asymmetric unit of the title salt, C(8)H(14)N(2) (2+)·2NO(3) (−), contains two independent dications and four independent nitrate anions. The crystal structure consists of discrete nitrate ions, three of which stack in layers parallel to (001) at z = 0 and 0.5. These layers are connected via m-x...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998625/ https://www.ncbi.nlm.nih.gov/pubmed/24826118 http://dx.doi.org/10.1107/S1600536814004620 |
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author | Gatfaoui, Sofian Dhaouadi, Hassouna Roisnel, Thierry Rzaigui, Mohamed Marouani, Houda |
author_facet | Gatfaoui, Sofian Dhaouadi, Hassouna Roisnel, Thierry Rzaigui, Mohamed Marouani, Houda |
author_sort | Gatfaoui, Sofian |
collection | PubMed |
description | The asymmetric unit of the title salt, C(8)H(14)N(2) (2+)·2NO(3) (−), contains two independent dications and four independent nitrate anions. The crystal structure consists of discrete nitrate ions, three of which stack in layers parallel to (001) at z = 0 and 0.5. These layers are connected via m-xylylenediaminium dications. The fourth anion is sandwiched by the two independent organic cations in the asymmetric unit. In the crystal, the ions are connected by a large number of bifurcated and non-bifurcated N—H⋯O(O) hydrogen bonds, forming sheets parallel to (100). These sheets are connected by C—H⋯O hydrogen bonds, forming a three-dimensional network. |
format | Online Article Text |
id | pubmed-3998625 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39986252014-05-13 m-Xylylenediaminium dinitrate Gatfaoui, Sofian Dhaouadi, Hassouna Roisnel, Thierry Rzaigui, Mohamed Marouani, Houda Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title salt, C(8)H(14)N(2) (2+)·2NO(3) (−), contains two independent dications and four independent nitrate anions. The crystal structure consists of discrete nitrate ions, three of which stack in layers parallel to (001) at z = 0 and 0.5. These layers are connected via m-xylylenediaminium dications. The fourth anion is sandwiched by the two independent organic cations in the asymmetric unit. In the crystal, the ions are connected by a large number of bifurcated and non-bifurcated N—H⋯O(O) hydrogen bonds, forming sheets parallel to (100). These sheets are connected by C—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2014-03-05 /pmc/articles/PMC3998625/ /pubmed/24826118 http://dx.doi.org/10.1107/S1600536814004620 Text en © Gatfaoui et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Gatfaoui, Sofian Dhaouadi, Hassouna Roisnel, Thierry Rzaigui, Mohamed Marouani, Houda m-Xylylenediaminium dinitrate |
title |
m-Xylylenediaminium dinitrate |
title_full |
m-Xylylenediaminium dinitrate |
title_fullStr |
m-Xylylenediaminium dinitrate |
title_full_unstemmed |
m-Xylylenediaminium dinitrate |
title_short |
m-Xylylenediaminium dinitrate |
title_sort | m-xylylenediaminium dinitrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998625/ https://www.ncbi.nlm.nih.gov/pubmed/24826118 http://dx.doi.org/10.1107/S1600536814004620 |
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