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m-Xylylenediaminium dinitrate

The asymmetric unit of the title salt, C(8)H(14)N(2) (2+)·2NO(3) (−), contains two independent dications and four independent nitrate anions. The crystal structure consists of discrete nitrate ions, three of which stack in layers parallel to (001) at z = 0 and 0.5. These layers are connected via m-x...

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Autores principales: Gatfaoui, Sofian, Dhaouadi, Hassouna, Roisnel, Thierry, Rzaigui, Mohamed, Marouani, Houda
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998625/
https://www.ncbi.nlm.nih.gov/pubmed/24826118
http://dx.doi.org/10.1107/S1600536814004620
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author Gatfaoui, Sofian
Dhaouadi, Hassouna
Roisnel, Thierry
Rzaigui, Mohamed
Marouani, Houda
author_facet Gatfaoui, Sofian
Dhaouadi, Hassouna
Roisnel, Thierry
Rzaigui, Mohamed
Marouani, Houda
author_sort Gatfaoui, Sofian
collection PubMed
description The asymmetric unit of the title salt, C(8)H(14)N(2) (2+)·2NO(3) (−), contains two independent dications and four independent nitrate anions. The crystal structure consists of discrete nitrate ions, three of which stack in layers parallel to (001) at z = 0 and 0.5. These layers are connected via m-xylylenediaminium dications. The fourth anion is sandwiched by the two independent organic cations in the asymmetric unit. In the crystal, the ions are connected by a large number of bifurcated and non-bifurcated N—H⋯O(O) hydrogen bonds, forming sheets parallel to (100). These sheets are connected by C—H⋯O hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-39986252014-05-13 m-Xylylenediaminium dinitrate Gatfaoui, Sofian Dhaouadi, Hassouna Roisnel, Thierry Rzaigui, Mohamed Marouani, Houda Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title salt, C(8)H(14)N(2) (2+)·2NO(3) (−), contains two independent dications and four independent nitrate anions. The crystal structure consists of discrete nitrate ions, three of which stack in layers parallel to (001) at z = 0 and 0.5. These layers are connected via m-xylylenediaminium dications. The fourth anion is sandwiched by the two independent organic cations in the asymmetric unit. In the crystal, the ions are connected by a large number of bifurcated and non-bifurcated N—H⋯O(O) hydrogen bonds, forming sheets parallel to (100). These sheets are connected by C—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2014-03-05 /pmc/articles/PMC3998625/ /pubmed/24826118 http://dx.doi.org/10.1107/S1600536814004620 Text en © Gatfaoui et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gatfaoui, Sofian
Dhaouadi, Hassouna
Roisnel, Thierry
Rzaigui, Mohamed
Marouani, Houda
m-Xylylenediaminium dinitrate
title m-Xylylenediaminium dinitrate
title_full m-Xylylenediaminium dinitrate
title_fullStr m-Xylylenediaminium dinitrate
title_full_unstemmed m-Xylylenediaminium dinitrate
title_short m-Xylylenediaminium dinitrate
title_sort m-xylylenediaminium dinitrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998625/
https://www.ncbi.nlm.nih.gov/pubmed/24826118
http://dx.doi.org/10.1107/S1600536814004620
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