Cargando…

Tetra­ethyl­ammonium 7,12-di­cyano-1-carba-closo-dodeca­borate

In the title compound, C(8)H(20)N(+)·C(3)H(10)B(11)N(2) (−), the carborane anion cage displays nearly-perfect C(s) symmetry, with the two CN groups lying on a noncrystallographic mirror plane that bis­ects the cage. In the crystal, the anions form extended chains along the a-axis direction, with C—H...

Descripción completa

Detalles Bibliográficos
Autores principales: Juhasz, Marcus A., Juers, Douglas H., Dwulet, Gregory E., Rosenbaum, Aaron J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998626/
https://www.ncbi.nlm.nih.gov/pubmed/24826126
http://dx.doi.org/10.1107/S1600536814004759
Descripción
Sumario:In the title compound, C(8)H(20)N(+)·C(3)H(10)B(11)N(2) (−), the carborane anion cage displays nearly-perfect C(s) symmetry, with the two CN groups lying on a noncrystallographic mirror plane that bis­ects the cage. In the crystal, the anions form extended chains along the a-axis direction, with C—H⋯N hydrogen bonds linking consecutive anions. The C N bond lengths (and B—C N angles) in the nitrile moities are 1.1201 (19) Å, 178.60 (15)° and 1.1433 (17) Å, 179.45 (15)°, similar to those observed in organic nitriles. A hydrogen bond between a methylene H atom of the cation and the N atom in one of the nitrile groups of the anion is the closest contact between the anion and cation, at 2.52 Å.