Tri­phenyl­tellurium chloride

The asymmetric unit of the title compound, C(18)H(15)ClTe, contains two mol­ecules which are in inverted orientations. The compound displays a tetra­hedral geometry around the Te atom in spite of there being five electron domains. This is attributed to the fact that the lone pair is not sterically a...

Descripción completa

Detalles Bibliográficos
Autores principales: Chopra, Ambika, Jain, Shalini, Srivastava, Sanjay K., Gupta, Sushil K., Butcher, Ray J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998628/
https://www.ncbi.nlm.nih.gov/pubmed/24826133
http://dx.doi.org/10.1107/S160053681400498X
_version_ 1782313403271872512
author Chopra, Ambika
Jain, Shalini
Srivastava, Sanjay K.
Gupta, Sushil K.
Butcher, Ray J.
author_facet Chopra, Ambika
Jain, Shalini
Srivastava, Sanjay K.
Gupta, Sushil K.
Butcher, Ray J.
author_sort Chopra, Ambika
collection PubMed
description The asymmetric unit of the title compound, C(18)H(15)ClTe, contains two mol­ecules which are in inverted orientations. The compound displays a tetra­hedral geometry around the Te atom in spite of there being five electron domains. This is attributed to the fact that the lone pair is not sterically active. The dihedral angles between the three phenyl rings are 76.51 (16)/73.75 (16)/71.06 (17) and 78.60 (17)/77.67 (16)/79.11 (16)° in the two mol­ecules. The crystal packing features eight C—H⋯π inter­actions.
format Online
Article
Text
id pubmed-3998628
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-39986282014-05-13 Tri­phenyl­tellurium chloride Chopra, Ambika Jain, Shalini Srivastava, Sanjay K. Gupta, Sushil K. Butcher, Ray J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(18)H(15)ClTe, contains two mol­ecules which are in inverted orientations. The compound displays a tetra­hedral geometry around the Te atom in spite of there being five electron domains. This is attributed to the fact that the lone pair is not sterically active. The dihedral angles between the three phenyl rings are 76.51 (16)/73.75 (16)/71.06 (17) and 78.60 (17)/77.67 (16)/79.11 (16)° in the two mol­ecules. The crystal packing features eight C—H⋯π inter­actions. International Union of Crystallography 2014-03-12 /pmc/articles/PMC3998628/ /pubmed/24826133 http://dx.doi.org/10.1107/S160053681400498X Text en © Chopra et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chopra, Ambika
Jain, Shalini
Srivastava, Sanjay K.
Gupta, Sushil K.
Butcher, Ray J.
Tri­phenyl­tellurium chloride
title Tri­phenyl­tellurium chloride
title_full Tri­phenyl­tellurium chloride
title_fullStr Tri­phenyl­tellurium chloride
title_full_unstemmed Tri­phenyl­tellurium chloride
title_short Tri­phenyl­tellurium chloride
title_sort tri­phenyl­tellurium chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998628/
https://www.ncbi.nlm.nih.gov/pubmed/24826133
http://dx.doi.org/10.1107/S160053681400498X
work_keys_str_mv AT chopraambika triphenyltelluriumchloride
AT jainshalini triphenyltelluriumchloride
AT srivastavasanjayk triphenyltelluriumchloride
AT guptasushilk triphenyltelluriumchloride
AT butcherrayj triphenyltelluriumchloride

Ejemplares similares