Cargando…

(E)-2-{[(Furan-2-ylmeth­yl)imino]­meth­yl}-4-nitro­phenol

In the title compound, C(12)H(10)N(2)O(4), the furan-2-ylmethyl group is disordered over two sets of sites, with refined occupancies of 0.858 (3) and 0.143 (3). In the major component of disorder, the dihedral angle between the furan and benzene rings is 63.1 (2)° and for the minor component this va...

Descripción completa

Detalles Bibliográficos
Autores principales: Hijji, Yousef, Azemati, Samira, Butcher, Ray J., Jasinski, Jerry P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998629/
https://www.ncbi.nlm.nih.gov/pubmed/24826153
http://dx.doi.org/10.1107/S1600536814005583
_version_ 1782313403514093568
author Hijji, Yousef
Azemati, Samira
Butcher, Ray J.
Jasinski, Jerry P.
author_facet Hijji, Yousef
Azemati, Samira
Butcher, Ray J.
Jasinski, Jerry P.
author_sort Hijji, Yousef
collection PubMed
description In the title compound, C(12)H(10)N(2)O(4), the furan-2-ylmethyl group is disordered over two sets of sites, with refined occupancies of 0.858 (3) and 0.143 (3). In the major component of disorder, the dihedral angle between the furan and benzene rings is 63.1 (2)° and for the minor component this value is 67.9 (6)°. The planes of the nitro group and the attached benzene ring form a dihedral angle of 4.34 (17)°. In the crystal, inversion-related mol­ecules are linked by two pairs of weak C—H⋯O inter­actions, one involving the nitro group and the other involving the O—H group as an acceptor. As a result of these associations, ribbons are formed along [120]. A strong intra­molecular O—H⋯N hydrogen bond is observed.
format Online
Article
Text
id pubmed-3998629
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-39986292014-05-13 (E)-2-{[(Furan-2-ylmeth­yl)imino]­meth­yl}-4-nitro­phenol Hijji, Yousef Azemati, Samira Butcher, Ray J. Jasinski, Jerry P. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(10)N(2)O(4), the furan-2-ylmethyl group is disordered over two sets of sites, with refined occupancies of 0.858 (3) and 0.143 (3). In the major component of disorder, the dihedral angle between the furan and benzene rings is 63.1 (2)° and for the minor component this value is 67.9 (6)°. The planes of the nitro group and the attached benzene ring form a dihedral angle of 4.34 (17)°. In the crystal, inversion-related mol­ecules are linked by two pairs of weak C—H⋯O inter­actions, one involving the nitro group and the other involving the O—H group as an acceptor. As a result of these associations, ribbons are formed along [120]. A strong intra­molecular O—H⋯N hydrogen bond is observed. International Union of Crystallography 2014-03-15 /pmc/articles/PMC3998629/ /pubmed/24826153 http://dx.doi.org/10.1107/S1600536814005583 Text en © Hijji et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hijji, Yousef
Azemati, Samira
Butcher, Ray J.
Jasinski, Jerry P.
(E)-2-{[(Furan-2-ylmeth­yl)imino]­meth­yl}-4-nitro­phenol
title (E)-2-{[(Furan-2-ylmeth­yl)imino]­meth­yl}-4-nitro­phenol
title_full (E)-2-{[(Furan-2-ylmeth­yl)imino]­meth­yl}-4-nitro­phenol
title_fullStr (E)-2-{[(Furan-2-ylmeth­yl)imino]­meth­yl}-4-nitro­phenol
title_full_unstemmed (E)-2-{[(Furan-2-ylmeth­yl)imino]­meth­yl}-4-nitro­phenol
title_short (E)-2-{[(Furan-2-ylmeth­yl)imino]­meth­yl}-4-nitro­phenol
title_sort (e)-2-{[(furan-2-ylmeth­yl)imino]­meth­yl}-4-nitro­phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998629/
https://www.ncbi.nlm.nih.gov/pubmed/24826153
http://dx.doi.org/10.1107/S1600536814005583
work_keys_str_mv AT hijjiyousef e2furan2ylmethyliminomethyl4nitrophenol
AT azematisamira e2furan2ylmethyliminomethyl4nitrophenol
AT butcherrayj e2furan2ylmethyliminomethyl4nitrophenol
AT jasinskijerryp e2furan2ylmethyliminomethyl4nitrophenol