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(E)-2-{[(Furan-2-ylmethyl)imino]methyl}-4-nitrophenol
In the title compound, C(12)H(10)N(2)O(4), the furan-2-ylmethyl group is disordered over two sets of sites, with refined occupancies of 0.858 (3) and 0.143 (3). In the major component of disorder, the dihedral angle between the furan and benzene rings is 63.1 (2)° and for the minor component this va...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998629/ https://www.ncbi.nlm.nih.gov/pubmed/24826153 http://dx.doi.org/10.1107/S1600536814005583 |
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author | Hijji, Yousef Azemati, Samira Butcher, Ray J. Jasinski, Jerry P. |
author_facet | Hijji, Yousef Azemati, Samira Butcher, Ray J. Jasinski, Jerry P. |
author_sort | Hijji, Yousef |
collection | PubMed |
description | In the title compound, C(12)H(10)N(2)O(4), the furan-2-ylmethyl group is disordered over two sets of sites, with refined occupancies of 0.858 (3) and 0.143 (3). In the major component of disorder, the dihedral angle between the furan and benzene rings is 63.1 (2)° and for the minor component this value is 67.9 (6)°. The planes of the nitro group and the attached benzene ring form a dihedral angle of 4.34 (17)°. In the crystal, inversion-related molecules are linked by two pairs of weak C—H⋯O interactions, one involving the nitro group and the other involving the O—H group as an acceptor. As a result of these associations, ribbons are formed along [120]. A strong intramolecular O—H⋯N hydrogen bond is observed. |
format | Online Article Text |
id | pubmed-3998629 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39986292014-05-13 (E)-2-{[(Furan-2-ylmethyl)imino]methyl}-4-nitrophenol Hijji, Yousef Azemati, Samira Butcher, Ray J. Jasinski, Jerry P. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(10)N(2)O(4), the furan-2-ylmethyl group is disordered over two sets of sites, with refined occupancies of 0.858 (3) and 0.143 (3). In the major component of disorder, the dihedral angle between the furan and benzene rings is 63.1 (2)° and for the minor component this value is 67.9 (6)°. The planes of the nitro group and the attached benzene ring form a dihedral angle of 4.34 (17)°. In the crystal, inversion-related molecules are linked by two pairs of weak C—H⋯O interactions, one involving the nitro group and the other involving the O—H group as an acceptor. As a result of these associations, ribbons are formed along [120]. A strong intramolecular O—H⋯N hydrogen bond is observed. International Union of Crystallography 2014-03-15 /pmc/articles/PMC3998629/ /pubmed/24826153 http://dx.doi.org/10.1107/S1600536814005583 Text en © Hijji et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Hijji, Yousef Azemati, Samira Butcher, Ray J. Jasinski, Jerry P. (E)-2-{[(Furan-2-ylmethyl)imino]methyl}-4-nitrophenol |
title | (E)-2-{[(Furan-2-ylmethyl)imino]methyl}-4-nitrophenol |
title_full | (E)-2-{[(Furan-2-ylmethyl)imino]methyl}-4-nitrophenol |
title_fullStr | (E)-2-{[(Furan-2-ylmethyl)imino]methyl}-4-nitrophenol |
title_full_unstemmed | (E)-2-{[(Furan-2-ylmethyl)imino]methyl}-4-nitrophenol |
title_short | (E)-2-{[(Furan-2-ylmethyl)imino]methyl}-4-nitrophenol |
title_sort | (e)-2-{[(furan-2-ylmethyl)imino]methyl}-4-nitrophenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998629/ https://www.ncbi.nlm.nih.gov/pubmed/24826153 http://dx.doi.org/10.1107/S1600536814005583 |
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