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9-(2-Chlorophenyl)-4a-hydroxy-3,4,4a,5,6,7,9,9a-octahydro-2H-xanthene-1,8-dione
In the title compound, C(19)H(19)ClO(4), the dihydropyran ring and the cyclohexane ring adopt a half-chair conformation and a chair conformation, respectively. The cyclohexene ring has an envelope conformation with the central CH(2) C atom as the flap. This atom is disordered over two positions...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998631/ https://www.ncbi.nlm.nih.gov/pubmed/24826146 http://dx.doi.org/10.1107/S1600536814005297 |
Sumario: | In the title compound, C(19)H(19)ClO(4), the dihydropyran ring and the cyclohexane ring adopt a half-chair conformation and a chair conformation, respectively. The cyclohexene ring has an envelope conformation with the central CH(2) C atom as the flap. This atom is disordered over two positions [site-occupancy ratio = 0.744 (12):0.256 (12)] above and below the mean plane formed by the other five atoms. In the crystal, O—H⋯O hydrogen bonds between hydroxy and carbonyl groups link molecules into chains propagating along [001]. |
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