Dye-sensitized Pt@TiO(2) core–shell nanostructures for the efficient photocatalytic generation of hydrogen

Pt@TiO(2) core–shell nanostructures were prepared through a hydrothermal method. The dye-sensitization of these Pt@TiO(2) core–shell structures allows for a high photocatalytic activity for the generation of hydrogen from proton reduction under visible-light irradiation. When the dyes and TiO(2) were co-excited through the combination of two irradiation beams with different wavelengths, a synergic effect was observed, which led to a greatly enhanced H(2) generation yield. This is attributed to the rational spatial distribution of the three components (dye, TiO(2), Pt), and the vectored transport of photogenerated electrons from the dye to the Pt particles via the TiO(2) particle bridge.