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Synthesis of chiral N-phosphinyl α-imino esters and their application in asymmetric synthesis of α-amino esters by reduction
A variety of chiral N-phosphinyl α-imino esters have been synthesized for the first time from ketoesters and phosphinylamide, which were then reduced by L-selectride to give the corresponding N-phosphinyl-protected α-amino esters. The reduction proceeded very well with excellent chemical yields (88–...
Autores principales: | Xiong, Yiwen, Mei, Haibo, Wu, Lingmin, Han, Jianlin, Pan, Yi, Li, Guigen |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3999852/ https://www.ncbi.nlm.nih.gov/pubmed/24778716 http://dx.doi.org/10.3762/bjoc.10.57 |
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