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Thermodynamically stable [4 + 2] cycloadducts of lanthanum-encapsulated endohedral metallofullerenes
The [4 + 2] cycloaddition of o-quinodimethanes, generated in situ from the sultine 4,5-benzo-3,6-dihydro-1,2-oxathiin 2-oxide and its derivative, to La metal-encapsulated fullerenes, La(2)@C(80) or La@C(82), afforded the novel derivatives of endohedral metallofullerenes (3a,b, 4a,b and 5b). Molecula...
Autores principales: | Takano, Yuta, Nagashima, Yuki, Herranz, M Ángeles, Martín, Nazario, Akasaka, Takeshi |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3999875/ https://www.ncbi.nlm.nih.gov/pubmed/24778724 http://dx.doi.org/10.3762/bjoc.10.65 |
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