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δ-Deuterium Isotope Effects as Probes for Transition-State Structures of Isoprenoid Substrates
[Image: see text] The biosynthetic pathways to isoprenoid compounds involve transfer of the prenyl moiety in allylic diphosphates to electron-rich (nucleophilic) acceptors. The acceptors can be many types of nucleophiles, while the allylic diphosphates only differ in the number of isoprene units and...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4004232/ https://www.ncbi.nlm.nih.gov/pubmed/24665882 http://dx.doi.org/10.1021/jo500394u |