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δ-Deuterium Isotope Effects as Probes for Transition-State Structures of Isoprenoid Substrates

[Image: see text] The biosynthetic pathways to isoprenoid compounds involve transfer of the prenyl moiety in allylic diphosphates to electron-rich (nucleophilic) acceptors. The acceptors can be many types of nucleophiles, while the allylic diphosphates only differ in the number of isoprene units and...

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Detalles Bibliográficos
Autores principales:	Choi, Seoung-ryoung, Breugst, Martin, Houk, Kendall N., Poulter, C. Dale
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4004232/ https://www.ncbi.nlm.nih.gov/pubmed/24665882 http://dx.doi.org/10.1021/jo500394u

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