Cargando…
General Allylic C–H Alkylation with Tertiary Nucleophiles
[Image: see text] A general method for intermolecular allylic C–H alkylation of terminal olefins with tertiary nucleophiles has been accomplished employing palladium(II)/bis(sulfoxide) catalysis. Allylic C–H alkylation furnishes products in good yields (avg. 64%) with excellent regio- and stereosele...
Autores principales: | Howell, Jennifer M., Liu, Wei, Young, Andrew J., White, M. Christina |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2014
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4004237/ https://www.ncbi.nlm.nih.gov/pubmed/24641574 http://dx.doi.org/10.1021/ja500726e |
Ejemplares similares
-
Palladium-catalyzed asymmetric allylic alkylation (AAA) with alkyl sulfones as nucleophiles
por: Trost, Barry M., et al.
Publicado: (2021) -
Pd-catalyzed asymmetric allylic alkylations via C–H activation of N-allyl imines with glycinates
por: Trost, Barry M., et al.
Publicado: (2017) -
Heterolysis of Dihydrogen by Nucleophilic Calcium Alkyls
por: Wilson, Andrew S. S., et al.
Publicado: (2018) -
Palladium Catalyzed Allylic C-H Alkylation: A Mechanistic Perspective
por: Engelin, Casper Junker, et al.
Publicado: (2011) -
Light-Triggered Catalytic
Asymmetric Allylic Benzylation
with Photogenerated C-Nucleophiles
por: Paria, Suva, et al.
Publicado: (2020)