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Oxacycle Synthesis via Intramolecular Reaction of Carbanions and Peroxides

[Image: see text] The intramolecular reaction of dialkyl peroxides with carbanions, generated via chemoselective metal-heteroatom exchange or deprotonation, provides a new approach to cyclic ethers. Applied in tandem with C–C bond formation, the strategy enables a one-step annelation to form oxaospi...

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Detalles Bibliográficos
Autores principales:	Willand-Charnley, Rachel, Puffer, Benjamin W., Dussault, Patrick H.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4004269/ https://www.ncbi.nlm.nih.gov/pubmed/24702123 http://dx.doi.org/10.1021/ja5026276

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