N,N′-Dimethyl-N′′-(trichloroacet­yl)phospho­ramide

In the title compound, C(4)H(9)Cl(3)N(3)O(2)P or CCl(3)C(O)NHP(O)(NHCH(3))(2), the P atom has a strongly distorted tetra­hedral geometry due to the formation of intermolecular strong hydrogen bonds involving the N atoms. In the crystal, N—H⋯O=P and N—H⋯O=C hydrogen bonds connect the mol­ecules into...

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Detalles Bibliográficos
Autor principal: Ovchynnikov, Vladimir
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4004432/
https://www.ncbi.nlm.nih.gov/pubmed/24860288
http://dx.doi.org/10.1107/S1600536813030389
Descripción
Sumario:In the title compound, C(4)H(9)Cl(3)N(3)O(2)P or CCl(3)C(O)NHP(O)(NHCH(3))(2), the P atom has a strongly distorted tetra­hedral geometry due to the formation of intermolecular strong hydrogen bonds involving the N atoms. In the crystal, N—H⋯O=P and N—H⋯O=C hydrogen bonds connect the mol­ecules into a two-dimensional array parallel to (100). An intra­molecular P⋯O contact [P⋯O = 2.975 (3) Å] is observed. The CCl(3) group is rotationally disordered, with occupancies of 0.60 (3) and 0.40 (3)

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