N,N′-Dimethyl-N′′-(trichloroacet­yl)phospho­ramide

In the title compound, C(4)H(9)Cl(3)N(3)O(2)P or CCl(3)C(O)NHP(O)(NHCH(3))(2), the P atom has a strongly distorted tetra­hedral geometry due to the formation of intermolecular strong hydrogen bonds involving the N atoms. In the crystal, N—H⋯O=P and N—H⋯O=C hydrogen bonds connect the mol­ecules into...

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Detalles Bibliográficos
Autor principal: Ovchynnikov, Vladimir
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4004432/
https://www.ncbi.nlm.nih.gov/pubmed/24860288
http://dx.doi.org/10.1107/S1600536813030389
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author Ovchynnikov, Vladimir
author_facet Ovchynnikov, Vladimir
author_sort Ovchynnikov, Vladimir
collection PubMed
description In the title compound, C(4)H(9)Cl(3)N(3)O(2)P or CCl(3)C(O)NHP(O)(NHCH(3))(2), the P atom has a strongly distorted tetra­hedral geometry due to the formation of intermolecular strong hydrogen bonds involving the N atoms. In the crystal, N—H⋯O=P and N—H⋯O=C hydrogen bonds connect the mol­ecules into a two-dimensional array parallel to (100). An intra­molecular P⋯O contact [P⋯O = 2.975 (3) Å] is observed. The CCl(3) group is rotationally disordered, with occupancies of 0.60 (3) and 0.40 (3)
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spelling pubmed-40044322014-05-23 N,N′-Dimethyl-N′′-(trichloroacet­yl)phospho­ramide Ovchynnikov, Vladimir Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(4)H(9)Cl(3)N(3)O(2)P or CCl(3)C(O)NHP(O)(NHCH(3))(2), the P atom has a strongly distorted tetra­hedral geometry due to the formation of intermolecular strong hydrogen bonds involving the N atoms. In the crystal, N—H⋯O=P and N—H⋯O=C hydrogen bonds connect the mol­ecules into a two-dimensional array parallel to (100). An intra­molecular P⋯O contact [P⋯O = 2.975 (3) Å] is observed. The CCl(3) group is rotationally disordered, with occupancies of 0.60 (3) and 0.40 (3) International Union of Crystallography 2013-11-09 /pmc/articles/PMC4004432/ /pubmed/24860288 http://dx.doi.org/10.1107/S1600536813030389 Text en © Vladimir Ovchynnikov 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ovchynnikov, Vladimir
N,N′-Dimethyl-N′′-(trichloroacet­yl)phospho­ramide
title N,N′-Dimethyl-N′′-(trichloroacet­yl)phospho­ramide
title_full N,N′-Dimethyl-N′′-(trichloroacet­yl)phospho­ramide
title_fullStr N,N′-Dimethyl-N′′-(trichloroacet­yl)phospho­ramide
title_full_unstemmed N,N′-Dimethyl-N′′-(trichloroacet­yl)phospho­ramide
title_short N,N′-Dimethyl-N′′-(trichloroacet­yl)phospho­ramide
title_sort n,n′-dimethyl-n′′-(trichloroacet­yl)phospho­ramide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4004432/
https://www.ncbi.nlm.nih.gov/pubmed/24860288
http://dx.doi.org/10.1107/S1600536813030389
work_keys_str_mv AT ovchynnikovvladimir nndimethylntrichloroacetylphosphoramide

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