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2-Methoxy-3-(trimethylsilyl)phenylboronic acid
The molecular structure of the title compound, C(10)H(17)BO(3)Si, features an intramolecular O—H⋯O hydrogen bond; the boronic group group has an exo–endo conformation. In the crystal, the molecules interact with each other by O—H⋯O hydrogen bonds, producing centrosymmetric dimers that are linked...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4004439/ https://www.ncbi.nlm.nih.gov/pubmed/24860295 http://dx.doi.org/10.1107/S1600536813031656 |
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author | Durka, Krzysztof Luliński, Sergiusz Serwatowski, Janusz |
author_facet | Durka, Krzysztof Luliński, Sergiusz Serwatowski, Janusz |
author_sort | Durka, Krzysztof |
collection | PubMed |
description | The molecular structure of the title compound, C(10)H(17)BO(3)Si, features an intramolecular O—H⋯O hydrogen bond; the boronic group group has an exo–endo conformation. In the crystal, the molecules interact with each other by O—H⋯O hydrogen bonds, producing centrosymmetric dimers that are linked by weak π–π stacking interactions featuring specific short B⋯C contacts [e.g. 3.372 (2) Å], forming an infinite columnar structure aligned along the a-axis direction. |
format | Online Article Text |
id | pubmed-4004439 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-40044392014-05-23 2-Methoxy-3-(trimethylsilyl)phenylboronic acid Durka, Krzysztof Luliński, Sergiusz Serwatowski, Janusz Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecular structure of the title compound, C(10)H(17)BO(3)Si, features an intramolecular O—H⋯O hydrogen bond; the boronic group group has an exo–endo conformation. In the crystal, the molecules interact with each other by O—H⋯O hydrogen bonds, producing centrosymmetric dimers that are linked by weak π–π stacking interactions featuring specific short B⋯C contacts [e.g. 3.372 (2) Å], forming an infinite columnar structure aligned along the a-axis direction. International Union of Crystallography 2013-11-23 /pmc/articles/PMC4004439/ /pubmed/24860295 http://dx.doi.org/10.1107/S1600536813031656 Text en © Durka et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Durka, Krzysztof Luliński, Sergiusz Serwatowski, Janusz 2-Methoxy-3-(trimethylsilyl)phenylboronic acid |
title | 2-Methoxy-3-(trimethylsilyl)phenylboronic acid |
title_full | 2-Methoxy-3-(trimethylsilyl)phenylboronic acid |
title_fullStr | 2-Methoxy-3-(trimethylsilyl)phenylboronic acid |
title_full_unstemmed | 2-Methoxy-3-(trimethylsilyl)phenylboronic acid |
title_short | 2-Methoxy-3-(trimethylsilyl)phenylboronic acid |
title_sort | 2-methoxy-3-(trimethylsilyl)phenylboronic acid |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4004439/ https://www.ncbi.nlm.nih.gov/pubmed/24860295 http://dx.doi.org/10.1107/S1600536813031656 |
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