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4-[(tert-Butyl­diphenyl­sil­yloxy)meth­yl]pyridazin-3(2H)-one

In the title compound, C(21)H(24)N(2)O(2)Si, the carbonyl group of the heterocyclic ring and the O atom of the silyl ether group are placed toward opposite sides and the tert-butyl and pyridazinone moieties are anti-oriented across the Si—O bond [torsion angle = −168.44 (19)°]. In the crystal, mol­e...

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Autores principales: Costas-Lago, María Carmen, Costas, Tamara, Vila, Noemí, Besada, Pedro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4004440/
https://www.ncbi.nlm.nih.gov/pubmed/24860296
http://dx.doi.org/10.1107/S1600536813032212
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author Costas-Lago, María Carmen
Costas, Tamara
Vila, Noemí
Besada, Pedro
author_facet Costas-Lago, María Carmen
Costas, Tamara
Vila, Noemí
Besada, Pedro
author_sort Costas-Lago, María Carmen
collection PubMed
description In the title compound, C(21)H(24)N(2)O(2)Si, the carbonyl group of the heterocyclic ring and the O atom of the silyl ether group are placed toward opposite sides and the tert-butyl and pyridazinone moieties are anti-oriented across the Si—O bond [torsion angle = −168.44 (19)°]. In the crystal, mol­ecules are assembled into inversion dimers through co-operative N—H⋯O hydrogen bonds between the NH groups and O atoms of the pyridazinone rings of neighbouring mol­ecules. The dimers are linked by π–π inter­actions involving adjacent pyridazinone rings [centroid–centroid distance = 3.8095 (19) Å], generating ladder-like chains along the b-axis direction. The chains are further linked into a two-dimensional network parallel to the ab plane through weak C—H⋯π inter­actions.
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spelling pubmed-40044402014-05-23 4-[(tert-Butyl­diphenyl­sil­yloxy)meth­yl]pyridazin-3(2H)-one Costas-Lago, María Carmen Costas, Tamara Vila, Noemí Besada, Pedro Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(24)N(2)O(2)Si, the carbonyl group of the heterocyclic ring and the O atom of the silyl ether group are placed toward opposite sides and the tert-butyl and pyridazinone moieties are anti-oriented across the Si—O bond [torsion angle = −168.44 (19)°]. In the crystal, mol­ecules are assembled into inversion dimers through co-operative N—H⋯O hydrogen bonds between the NH groups and O atoms of the pyridazinone rings of neighbouring mol­ecules. The dimers are linked by π–π inter­actions involving adjacent pyridazinone rings [centroid–centroid distance = 3.8095 (19) Å], generating ladder-like chains along the b-axis direction. The chains are further linked into a two-dimensional network parallel to the ab plane through weak C—H⋯π inter­actions. International Union of Crystallography 2013-11-30 /pmc/articles/PMC4004440/ /pubmed/24860296 http://dx.doi.org/10.1107/S1600536813032212 Text en © Costas-Lago et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Costas-Lago, María Carmen
Costas, Tamara
Vila, Noemí
Besada, Pedro
4-[(tert-Butyl­diphenyl­sil­yloxy)meth­yl]pyridazin-3(2H)-one
title 4-[(tert-Butyl­diphenyl­sil­yloxy)meth­yl]pyridazin-3(2H)-one
title_full 4-[(tert-Butyl­diphenyl­sil­yloxy)meth­yl]pyridazin-3(2H)-one
title_fullStr 4-[(tert-Butyl­diphenyl­sil­yloxy)meth­yl]pyridazin-3(2H)-one
title_full_unstemmed 4-[(tert-Butyl­diphenyl­sil­yloxy)meth­yl]pyridazin-3(2H)-one
title_short 4-[(tert-Butyl­diphenyl­sil­yloxy)meth­yl]pyridazin-3(2H)-one
title_sort 4-[(tert-butyl­diphenyl­sil­yloxy)meth­yl]pyridazin-3(2h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4004440/
https://www.ncbi.nlm.nih.gov/pubmed/24860296
http://dx.doi.org/10.1107/S1600536813032212
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