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4-[(tert-Butyldiphenylsilyloxy)methyl]pyridazin-3(2H)-one
In the title compound, C(21)H(24)N(2)O(2)Si, the carbonyl group of the heterocyclic ring and the O atom of the silyl ether group are placed toward opposite sides and the tert-butyl and pyridazinone moieties are anti-oriented across the Si—O bond [torsion angle = −168.44 (19)°]. In the crystal, mole...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4004440/ https://www.ncbi.nlm.nih.gov/pubmed/24860296 http://dx.doi.org/10.1107/S1600536813032212 |
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author | Costas-Lago, María Carmen Costas, Tamara Vila, Noemí Besada, Pedro |
author_facet | Costas-Lago, María Carmen Costas, Tamara Vila, Noemí Besada, Pedro |
author_sort | Costas-Lago, María Carmen |
collection | PubMed |
description | In the title compound, C(21)H(24)N(2)O(2)Si, the carbonyl group of the heterocyclic ring and the O atom of the silyl ether group are placed toward opposite sides and the tert-butyl and pyridazinone moieties are anti-oriented across the Si—O bond [torsion angle = −168.44 (19)°]. In the crystal, molecules are assembled into inversion dimers through co-operative N—H⋯O hydrogen bonds between the NH groups and O atoms of the pyridazinone rings of neighbouring molecules. The dimers are linked by π–π interactions involving adjacent pyridazinone rings [centroid–centroid distance = 3.8095 (19) Å], generating ladder-like chains along the b-axis direction. The chains are further linked into a two-dimensional network parallel to the ab plane through weak C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-4004440 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-40044402014-05-23 4-[(tert-Butyldiphenylsilyloxy)methyl]pyridazin-3(2H)-one Costas-Lago, María Carmen Costas, Tamara Vila, Noemí Besada, Pedro Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(24)N(2)O(2)Si, the carbonyl group of the heterocyclic ring and the O atom of the silyl ether group are placed toward opposite sides and the tert-butyl and pyridazinone moieties are anti-oriented across the Si—O bond [torsion angle = −168.44 (19)°]. In the crystal, molecules are assembled into inversion dimers through co-operative N—H⋯O hydrogen bonds between the NH groups and O atoms of the pyridazinone rings of neighbouring molecules. The dimers are linked by π–π interactions involving adjacent pyridazinone rings [centroid–centroid distance = 3.8095 (19) Å], generating ladder-like chains along the b-axis direction. The chains are further linked into a two-dimensional network parallel to the ab plane through weak C—H⋯π interactions. International Union of Crystallography 2013-11-30 /pmc/articles/PMC4004440/ /pubmed/24860296 http://dx.doi.org/10.1107/S1600536813032212 Text en © Costas-Lago et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Costas-Lago, María Carmen Costas, Tamara Vila, Noemí Besada, Pedro 4-[(tert-Butyldiphenylsilyloxy)methyl]pyridazin-3(2H)-one |
title | 4-[(tert-Butyldiphenylsilyloxy)methyl]pyridazin-3(2H)-one |
title_full | 4-[(tert-Butyldiphenylsilyloxy)methyl]pyridazin-3(2H)-one |
title_fullStr | 4-[(tert-Butyldiphenylsilyloxy)methyl]pyridazin-3(2H)-one |
title_full_unstemmed | 4-[(tert-Butyldiphenylsilyloxy)methyl]pyridazin-3(2H)-one |
title_short | 4-[(tert-Butyldiphenylsilyloxy)methyl]pyridazin-3(2H)-one |
title_sort | 4-[(tert-butyldiphenylsilyloxy)methyl]pyridazin-3(2h)-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4004440/ https://www.ncbi.nlm.nih.gov/pubmed/24860296 http://dx.doi.org/10.1107/S1600536813032212 |
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