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Walphos versus Biferrocene-Based Walphos Analogues in the Asymmetric Hydrogenation of Alkenes and Ketones

[Image: see text] Two representative Walphos analogues with an achiral 2,2″-biferrocenediyl backbone were synthesized. These diphosphine ligands were tested in the rhodium-catalyzed asymmetric hydrogenation of several alkenes and in the ruthenium-catalyzed hydrogenation of two ketones. The results w...

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Detalles Bibliográficos
Autores principales: Zirakzadeh, Afrooz, Groß, Manuela A., Wang, Yaping, Mereiter, Kurt, Weissensteiner, Walter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4006446/
https://www.ncbi.nlm.nih.gov/pubmed/24795493
http://dx.doi.org/10.1021/om401074a

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